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Chemistry World
June 14, 2012
David Bradley
Tripling up on boron bonds Carbon and nitrogen are well known for their triple bonds, but making stable compounds with a triple bond between two boron atoms hadn't been achieved despite the computational possibilities. Until now. mark for My Articles similar articles
Chemistry World
November 24, 2014
Jennifer Newton
Boron and beryllium finally shake hands Beryllium bis(diazaborolyl) features the first non-cluster bond between boron and beryllium. mark for My Articles similar articles
Chemistry World
February 6, 2012
David Bradley
10 out of 10 for boron's coordinated effort A team in the US has created a boron compound that has the highest coordination number of any planar species, squeezing 10 spoke-like bonds from a central metal hub to 10 boron atoms equally spaced around a nanoscopic wheel. mark for My Articles similar articles
Chemistry World
July 8, 2010
Phillip Broadwith
Flattening carbon UK researchers have managed to synthesise a molecule with an almost planar four-coordinate carbon atom bonded to two lithium atoms and bulky organic ligands. mark for My Articles similar articles
Chemistry World
March 10, 2006
Dual Organometallics Enhance Zinc Reactivity Chemists have synthesised organometallic compounds that enable zinc to participate in directed metalation of organic substrates. mark for My Articles similar articles
Chemistry World
April 15, 2010
Simon Hadlington
Lead joins the aromatic ring club Scientists in Japan have successfully incorporated an atom of lead into an aromatic molecule - the heaviest metal so far to be 'aromatised'. mark for My Articles similar articles
Chemistry World
February 28, 2008
James Mitchell Crow
Chloride Ions in a Bind Chemists in the US have designed a donut-shaped molecule that tightly binds negatively-charged chloride ions. mark for My Articles similar articles
Chemistry World
December 10, 2008
Simon Hadlington
Alcohol enantiomer conundrum cracked UK chemists have discovered a straightforward new way to make chiral tertiary alcohols that gives selective access to either enantiomer. mark for My Articles similar articles
Chemistry World
December 18, 2012
Caryl Richards
Boron vapor trail leads to heterofullerenes A team of scientists has developed a simple way to synthesize heterofullerenes -- fullerenes with atoms other than carbon in their structure -- by exposing fullerene to boron vapor during their growth. mark for My Articles similar articles
Chemistry World
September 28, 2011
Laura Howes
Conjuring up gram quantities of a stabilising anion For a certain breed of inorganic chemist, weakly coordinating anions are great - they hardly interact with their positive counterparts and so can stabilise unstable cations. mark for My Articles similar articles
Chemistry World
March 2012
Column: In the pipeline Drug discovery requires experimentation, says Derek Lowe. But chemists can be reluctant to stray from the elements they know and love mark for My Articles similar articles
Chemistry World
March 22, 2012
Ross McLaren
Back to the future: old reactions to help the new Researchers from the US have delved into the history of organic chemistry to help chemists better predict the effect that functional groups will have on one another within a molecule. mark for My Articles similar articles
Chemistry World
May 28, 2015
Matthew Gunther
Purely inorganic aromatic ion synthesized Scientists in the US have successfully synthesized an aromatic ion made from only nitrogen and phosphorus. The anion is a rare example of a stable aromatic species containing no carbon atoms. mark for My Articles similar articles
Chemistry World
August 21, 2008
Fred Campbell
Double bonding with silicon In a landmark for silicon chemistry, US researchers have reported the first stable silicon (0) compound to contain a silicon-silicon double bond. mark for My Articles similar articles
Chemistry World
November 3, 2008
Simon Hadlington
Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple? mark for My Articles similar articles
Chemistry World
August 29, 2008
Fred Campbell
Breaking the bonds of global warming US scientists have managed to prise apart the highly unreactive carbon-fluorine bond at room temperature, potentially paving the way to the efficient disposal of hydrofluorocarbons -- highly stable and long-lived greenhouse gases. mark for My Articles similar articles
Reactive Reports
Issue 62
Alumination at last! More powerful solid rocket fuel could be the product of research into a new class of compounds containing aluminum and hydrogen compounds, according to an international research team. mark for My Articles similar articles
Chemistry World
July 29, 2013
Jennifer Newton
240 boron atoms in a single molecular species The unique supramolecular cuboctahedron contains 240 boron atoms and was synthesized by Chad Mirkin and colleagues at Northwestern University in Evanston, Illinois, via coordination-driven assembly. mark for My Articles similar articles
Chemistry World
October 31, 2013
Tim Wogan
Pressure to form exotic ionic salts irresistible for nitrogen Researchers have used computer algorithms to calculate nitrogen structures at pressures far beyond the reach of current experimental determinations. Most notably, they calculated that it could form an ionic salt in which both the cations and anions were nitrogen. mark for My Articles similar articles
Chemistry World
January 28, 2009
Manisha Lalloo
Ultra-pure boron structure discovered Scientists have characterised a new form of elemental boron - a notoriously hard element to synthesise in a pure form - and found that ionic bonding helps hold the structure together. mark for My Articles similar articles
Chemistry World
December 10, 2014
Emma Stoye
Cutting edge chemistry in 2014 Highlights from last year's ground breaking chemical sciences research. mark for My Articles similar articles
Chemistry World
May 16, 2010
Simon Hadlington
Anions enjoy a taste of pi European researchers have captured the moment when an anion interacts with the pi electron cloud of an aromatic molecule, something that has been known to occur but never seen at work. mark for My Articles similar articles
Chemistry World
January 24, 2010
Andy Extance
Boron cluster forms unique ring system Clusters of nineteen boron atoms gather together in a ring structure unlike any other seen, with two planar -bonded aromatic systems nestled inside one another. mark for My Articles similar articles
Chemistry World
January 19, 2007
Richard Van Noorden
Happy Families for Aluminium Chemists have discovered that aluminium - a notoriously anti-social element compared with its sister boron - may in fact form an unexpected family of hydride clusters. mark for My Articles similar articles
Science News
March 16, 2002
TimeLine: March 12, 1932 Scientists unearth new portrait of King Tut's girl-wife... Tapping of the atom's energy achieved in new experiment... Scientists learning secret of how plants manufacture food... mark for My Articles similar articles
Chemistry World
November 12, 2015
Tim Wogan
Flat boron first looks promising for nano-electronics The super hard material, which was formed by two-stage chemical vapor deposition, has unusual properties for a two-dimensional material that could potentially make it very useful in nano-electronics. mark for My Articles similar articles
Chemistry World
February 19, 2010
Simon Hadlington
Forcing stereoselectivity on reactive cations Chemists in the US have devised a dual catalyst strategy to tame the highly reactive iminium ion to give a high degree of stereochemical control over subsequent reactions of the ion. mark for My Articles similar articles
Chemistry World
June 21, 2007
Simon Hadlington
Boron is Key to Antifungal Agent Researchers have shown that the presence of a boron atom is key to an antifungal agent being developed to treat infections of fingernails and toenails. mark for My Articles similar articles
Chemistry World
December 2009
Paul Docherty
Column: Totally Synthetic What turns a good synthesis into a great synthesis are the steps surrounding that motif, something that Darren Dixon from the University of Oxford, UK, exemplifies with this synthesis of Nakadomarin A. mark for My Articles similar articles
Chemistry World
July 27, 2015
Anisha Ratan
Boroles get a stability boost Scientists from Germany have reported a breakthrough in borole stability, using bulky fluoromesityl groups, which could help these anti-aromatic molecules realize their potential in optoelectronic devices. mark for My Articles similar articles
Chemistry World
July 29, 2011
Simon Hadlington
Archetypal Lewis Acid Borane Turned Into a Base Chemists in the US and Germany have achieved the remarkable feat of transforming a borane, an archetypal electron-accepting Lewis acid, into an electron-donating Lewis base. mark for My Articles similar articles
Chemistry World
December 15, 2010
Hayley Birch
New technique probes electron properties of individual atoms A new, low voltage electron microscopy technique allows scientists to discriminate not just between atoms of different elements but between atoms of the same element in different electronic states. mark for My Articles similar articles
Chemistry World
July 14, 2014
Tim Wogan
First experimental evidence of a boron fullerene The first experimental evidence for a boron fullerene has been produced by researchers in the US and China. mark for My Articles similar articles
Chemistry World
January 24, 2013
Paul Docherty
Hyperforin Studies of St John's wort have found several biologically active ingredients, but the primary agent is hyperforin, a potent inhibitor of several neurotransmitters. mark for My Articles similar articles
Chemistry World
July 7, 2014
Jennifer Newton
Buckyball boron Systematic structure-searching calculations performed by scientists in China have put forward an all-boron analogue of fullerene: B 38. mark for My Articles similar articles
Chemistry World
January 29, 2015
Jennifer Newton
Graphene looks to doped superbenzene to overcome electronic hurdles Building graphene from carefully-modified superbenzene segments has been proposed as a way to help graphene overcome a major stumbling block limiting its application in electronic devices. mark for My Articles similar articles
Chemistry World
January 30, 2014
Jessica Cocker
Crystal structure highlights buckycatcher's flexibility Chemists in the US have successfully isolated the first anion of a distinctive type of pincer molecule, known as a buckycatcher, and confirmed the extraordinary flexibility it has for encapsulating guest molecules. mark for My Articles similar articles
Chemistry World
December 20, 2012
Laura Howes
Cutting edge chemistry in 2012 This year saw more work probing the nature of bonding. In Germany, Holger Braunschweig found that reacting a bis(N-heterocyclic carbene)-stabilized tetrabromodiborane with sodium naphthalene gave diborene or diboryne compounds with the world's first stable boron -- boron triple bond. mark for My Articles similar articles
Chemistry World
May 21, 2010
Simon Hadlington
H-bond partner-swapping seen in the flesh The dance moves that a water molecule makes as it flips hydrogen bonds from one partner to another have been captured by US researchers. mark for My Articles similar articles
National Defense
December 2010
Grace V. Jean
Advancing Hidden Nuclear Material Detection On any given day, ships and trucks deliver cargo containers filled with tons of imported goods. Homeland security officials have long warned that terrorists may use them to smuggle nuclear materials into the United States. mark for My Articles similar articles
Chemistry World
July 27, 2007
Richard Van Noorden
Space Monster Discovered Astrochemists who waited 25 years to find an anion in space have spotted three in less than a year. mark for My Articles similar articles
Chemistry World
November 12, 2015
Simon Hadlington
Jurassic pigment structure elucidation tickles chemists pink Chemists in Germany have elucidated the structure of an enigmatic pink pigment found in fossils of an alga that lived on Earth more than 150 million years ago. mark for My Articles similar articles
Chemistry World
July 28, 2014
Tim Wogan
Better batteries with pure lithium anodes Researchers in the US have developed a coating that could allow next generation batteries to have pure lithium anodes. mark for My Articles similar articles
Chemistry World
May 9, 2014
Helen Bache
Salt lakes worth their lithium Researchers in Japan have demonstrated the exceptional potential of a hydrated titanium oxide to extract lithium from salt lake brine collected from Salar de Uyuni in Bolivia, the world's largest salt flat. mark for My Articles similar articles
Technology Research News
August 11, 2004
Single gold atoms altered The gold atom, positioned on an ultrathin film of sodium chloride, remained stable during the operation, despite the change in charge. mark for My Articles similar articles
Chemistry World
May 10, 2012
Phillip Broadwith
Borosulfate breaks through Henning Hoppe, together with a team from the University of Augsburg and Albert Ludwigs University Freiburg in Germany, created potassium borosulfate - K 5[B(SO 4) 4] - by heating potassium sulfate with boric and sulfuric acids. mark for My Articles similar articles
Chemistry World
April 19, 2007
Lewis Brindley
Superhard Material Made at Ambient Pressure Inorganic chemists in the U.S. have synthesized a material that rivals the hardness of diamond, without needing to use extremely high pressure. mark for My Articles similar articles
Science News
October 19, 2002
TimeLine: October 15, 1932 The saber-tooth strikes... Dangers of dust in industry described at safety congress... Scientist directs huge magnet in attack to smash atom... mark for My Articles similar articles