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Chemistry World
January 20, 2010
James Urquhart
Disilicate synthesis success A compound containing a stable silicon-silicon bond between two negatively charged pentacoordinated silicon atoms - silicates - has been synthesized and isolated for the first time by Japanese researchers. mark for My Articles similar articles
Chemistry World
April 11, 2010
Simon Hadlington
Phosphorus fragments trapped Researchers in the US and Germany have shown how a rare and highly reactive form of phosphorus can be captured and crystallised, making it stable even at room temperature. mark for My Articles similar articles
Chemistry World
April 20, 2015
Andy Extance
Longer-lived oxides offer silicon synthesis boost Silicon and oxygen have been harnessed into previously unknown chemistry by US researchers, opening up a new 'world in a grain of sand'. mark for My Articles similar articles
Chemistry World
June 14, 2012
David Bradley
Tripling up on boron bonds Carbon and nitrogen are well known for their triple bonds, but making stable compounds with a triple bond between two boron atoms hadn't been achieved despite the computational possibilities. Until now. mark for My Articles similar articles
Chemistry World
January 29, 2010
Phillip Broadwith
Silicon goes aromatic Chemists in the UK have constructed a structural analogue of benzene made from silicon atoms. The molecule is not flat like benzene, but it reveals a new type of aromatic stabilisation. mark for My Articles similar articles
Chemistry World
February 8, 2006
Jon Evans
To Boldly go Where no Chemist Has Gone Before Studying the interactions between different molecular fragments is taking researchers to the uncharted regions of chemical space. mark for My Articles similar articles
Chemistry World
April 26, 2011
Manisha Lalloo
Pnicogens link up as new bond is discovered German researchers have discovered a chemical oddity - a new type of intramolecular interaction between group 15 atoms, which is as strong as a hydrogen bond. These interactions could be used to build supramolecular structures. mark for My Articles similar articles
Chemistry World
October 22, 2009
Simon Hadlington
Carbenes catalyse metal-metal bonds in organometallics Chemists in the US have discovered a novel way to transform organometallic compounds so that new metal-metal bonds are created. mark for My Articles similar articles
Reactive Reports
November 2007
David Bradley
Organic Uranium The first ever uranium methylidyne molecule has been synthesized by US chemists despite the reactivity of the heavy, heavy metal. mark for My Articles similar articles
Chemistry World
March 2010
Philip Ball
Column: The crucible Superatoms reinforce the notion that chemistry is more about electrons than elements, says the author mark for My Articles similar articles
Chemistry World
March 25, 2012
Phillip Broadwith
Germanium-Oxygen Double Bond Takes Centre Stage The first compound with a germanium-oxygen double bond has been created by Japanese scientists. mark for My Articles similar articles
Chemistry World
December 13, 2009
Lewis Brindley
Breaking the strongest bonds Chemists have uncovered a way to sever two of the strongest bonds in chemistry - in dinitrogen and carbon monoxide - and make useful organic compounds. mark for My Articles similar articles
Chemistry World
April 13, 2006
Jon Evans
Chemists Bring Alien Molecule Down to Earth Chemists have recreated an alien molecule in the laboratory by synthesising a stable version of the carbene cyclopropenylidene. Cyclopropenylidene was first detected by radio astronomers in 1985, and is now the most abundant cyclic hydrocarbon observed in interstellar space. mark for My Articles similar articles
Chemistry World
July 29, 2011
Simon Hadlington
Archetypal Lewis Acid Borane Turned Into a Base Chemists in the US and Germany have achieved the remarkable feat of transforming a borane, an archetypal electron-accepting Lewis acid, into an electron-donating Lewis base. mark for My Articles similar articles
Chemistry World
November 28, 2008
Manisha Lalloo
Elusive cation caught in a cage Chemists have isolated the elusive and highly reactive germanium dication by trapping it in a molecular cage. mark for My Articles similar articles
Chemistry World
May 22, 2008
Richard Van Noorden
Xenon doubled up with water Creating a water molecule with two noble gas atoms interpolated into its structure sounds an improbable feat, but a international team of researchers now claim to have trapped just such an exotic compound in xenon. mark for My Articles similar articles
Chemistry World
June 2008
Sarah Houlton
Breaking the rules The author finds out about some chemical tricks that can give a new drug the best possible odds of success mark for My Articles similar articles
Chemistry World
May 13, 2013
Philip Ball
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? mark for My Articles similar articles
Chemistry World
October 5, 2006
Mark Peplow
Boron Shows Its Negative Side A molecule that hosts a negatively-charged boron atom could prove to be an exciting addition to the chemist's toolbox, according to researchers who have isolated the anion as its lithium salt. mark for My Articles similar articles
Chemistry World
February 6, 2012
David Bradley
10 out of 10 for boron's coordinated effort A team in the US has created a boron compound that has the highest coordination number of any planar species, squeezing 10 spoke-like bonds from a central metal hub to 10 boron atoms equally spaced around a nanoscopic wheel. mark for My Articles similar articles
Chemistry World
March 21, 2007
Richard Van Noorden
Forcing a Reaction US chemists have forced molecules to react by ripping their bonds apart with ultrasound. The scientists carefully stretched one targeted bond until it snapped, guiding the molecule's subsequent reaction into pathways forbidden by conventional chemistry. mark for My Articles similar articles
Chemistry World
April 15, 2010
Simon Hadlington
Lead joins the aromatic ring club Scientists in Japan have successfully incorporated an atom of lead into an aromatic molecule - the heaviest metal so far to be 'aromatised'. mark for My Articles similar articles
Chemistry World
December 16, 2013
Tim Wogan
Calculations predict stable eight nitrogen molecule Nitrogen could form an N 8 molecular crystal at low temperatures, according to density functional theory calculations done by Israeli and US researchers. mark for My Articles similar articles
Chemistry World
September 29, 2015
Navigating chemical space How big is chemistry? I don't mean how important is it, or how many people do it, but rather, how many molecules are there that we could make? mark for My Articles similar articles
Chemistry World
November 3, 2008
Simon Hadlington
Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple? mark for My Articles similar articles
Chemistry World
December 20, 2007
Richard Van Noorden
Off-the-Peg Organic Synthesis Goes Commercial Chemists have created an efficient way to make small molecules by repeatedly using just one coupling reaction to clip together pre-prepared chemical fragments is going commercial. mark for My Articles similar articles
Chemistry World
May 29, 2015
Derek Lowe
Magic molecule modifiers The synthesis of a new organic molecule can be approached in several ways. mark for My Articles similar articles
Chemistry World
January 24, 2010
Andy Extance
Boron cluster forms unique ring system Clusters of nineteen boron atoms gather together in a ring structure unlike any other seen, with two planar -bonded aromatic systems nestled inside one another. mark for My Articles similar articles
Chemistry World
January 28, 2009
Manisha Lalloo
Ultra-pure boron structure discovered Scientists have characterised a new form of elemental boron - a notoriously hard element to synthesise in a pure form - and found that ionic bonding helps hold the structure together. mark for My Articles similar articles
Chemistry World
November 30, 2007
Lewis Brindley
Crystal Clear Structure Prediction One team of researchers has hit the jackpot by correctly predicting the crystal structures of four organic molecules in a competition organized by the University of Cambridge. mark for My Articles similar articles
Chemistry World
November 18, 2014
Tim Wogan
New silicon allotrope could revolutionize solar cells A new, direct band gap allotrope of silicon has been synthesized by researchers in the US. It could potentially revolutionize solar cells and light-emitting devices. mark for My Articles similar articles
Chemistry World
March 9, 2007
Michael Gross
Nanowires go Round the Bend Chemists have bent an apparently linear molecular wire into a closed circle, creating a conducting ring just 3 nanometers across. mark for My Articles similar articles
Chemistry World
March 5, 2007
Richard Van Noorden
Desperately Seeking Silicon Silicon has been blamed for the faulty fuel that caused thousands of UK cars to break down last week. How can a silvery-gray semi-metal popularly known to be used in computer chips have found its way into gasoline? mark for My Articles similar articles
Chemistry World
May 4, 2010
Lewis Brindley
Nanomachinery gets a spring in its step Molecular springs that always twist the same way are the latest addition to the nanomachinery toolbox. mark for My Articles similar articles
Chemistry World
September 24, 2009
Lewis Brindley
Nerve gas detection in a fraction of a second A new molecule that detects and destroys lethal nerve gases has been developed by researchers in the US. mark for My Articles similar articles
Chemistry World
September 12, 2010
Simon Hadlington
Isotope effect seen on single molecule The isotope effect - where the rate of a reaction is altered depending on the presence of a given isotopic atom in the reactant - is a key tool for elucidating reaction mechanisms mark for My Articles similar articles
Chemistry World
October 28, 2014
Derek Lowe
Chemical space is big. Really big. We are not going to run out of interesting and useful structures, and the uses that they could be put to are probably also beyond our imagining. In chemical space, we really do have an effectively endless frontier. mark for My Articles similar articles
Chemistry World
June 11, 2008
Simon Hadlington
Houdini Molecule Escapes Energy Trap A team of international chemists has captured and caught on camera a small, elusive molecule that has previously never been seen. mark for My Articles similar articles
Chemistry World
June 13, 2012
Simon Hadlington
Exploding molecule provides 3D bond images Researchers from the US and Germany have demonstrated a new way to obtain accurate three-dimensional images of molecules, with precise measurements of the geometry of the molecule's chemical bonds. mark for My Articles similar articles
Chemistry World
March 10, 2006
Dual Organometallics Enhance Zinc Reactivity Chemists have synthesised organometallic compounds that enable zinc to participate in directed metalation of organic substrates. mark for My Articles similar articles
Technology Research News
August 27, 2003
Light makes molecule shine Researchers from Kyushu University in Japan have constructed a fluorescent molecule that can be repeatedly switched on and off. If a way can be found to switch individual, closely-packed molecules on and off, fantastic amounts of information could be stored in very small spaces. mark for My Articles similar articles
Chemistry World
October 2008
Derek Lowe
Column: In the pipeline The author seeks a cure for 'compound bloat' mark for My Articles similar articles
Chemistry World
January 3, 2012
Simon Hadlington
One-pot synthesis creates anticancer candidates Researchers in Germany have developed a simple, rapid and high-yielding cascade synthesis of a collection of polycyclic compounds that resemble indole alkaloid natural products and which interfere with cell division. mark for My Articles similar articles
Chemistry World
March 2012
Column: In the pipeline Drug discovery requires experimentation, says Derek Lowe. But chemists can be reluctant to stray from the elements they know and love mark for My Articles similar articles
Chemistry World
October 7, 2014
Jennifer Newton
FBNCO: all the 2p-block elements in one molecule Scientists in Italy have made a molecule with one of each of the 2p-block elements. Well, almost. There's no neon in FBNCO but it would be a bit unfair to expect them to include an element with no known chemistry. mark for My Articles similar articles
Chemistry World
July 23, 2012
David Bradley
The buzz about finding new allotropes Researchers in China have homed in on possible new allotropes of carbon, silicon and germanium using a particle swarm structure search technique. mark for My Articles similar articles
Chemistry World
January 29, 2015
Santiago Alvarez
What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept. mark for My Articles similar articles
Reactive Reports
Issue 63
David Bradley
Chemists Go Round the Bend Chemists often think of molecular wires as "shape-persistent" rods with limited flexibility, but researchers have now shown that molecular wires can be bent into ring shapes. mark for My Articles similar articles
Chemistry World
May 12, 2011
Jon Cartwright
'Chemical soldering' heralds single molecule electronics Scientists in Japan and Switzerland have demonstrated how to wire up single molecules with conductive nanowires. mark for My Articles similar articles
IEEE Spectrum
March 2011
Saswato R. Das
A Crowd of Quantum Entanglements Phosphorus-in-silicon system could lead to quantum computers mark for My Articles similar articles