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Chemistry World April 15, 2010 Simon Hadlington |
Lead joins the aromatic ring club Scientists in Japan have successfully incorporated an atom of lead into an aromatic molecule - the heaviest metal so far to be 'aromatised'. |
Chemistry World October 9, 2014 Katrina Kramer |
Largest Mobius molecule synthesized Researchers from Korea and Japan have put a new twist on aromaticity, synthesizing the largest Mobius aromatic molecule to date. |
Chemistry World January 29, 2010 Phillip Broadwith |
Silicon goes aromatic Chemists in the UK have constructed a structural analogue of benzene made from silicon atoms. The molecule is not flat like benzene, but it reveals a new type of aromatic stabilisation. |
Chemistry World April 15, 2009 Phillip Broadwith |
Heteroaromatic rings of the future UK scientists have created a computer program to work out all the aromatic heterocycles that could be synthesised, hoping to expand the range of molecules used in the pharmaceutical and other industries. |
Reactive Reports David Bradley |
Subjective Suboxide Carbon monoxide and carbon dioxide are probably the best known molecules containing just carbon and oxygen, but they do form others, such as carbon suboxide (C3O2), which is one of the most stable. |
Chemistry World April 14, 2009 Lewis Brindley |
Osmium and pyridine ring together Organic chemists in China have found a way to put osmium into a pyridine ring - leading to the synthesis of the first metallapyridinium complex. |
Chemistry World May 30, 2012 Jon Cartwright |
Tiny buckyball grown around metal atom An international team of researchers has observed the smallest fullerene to form spontaneously to date using metal atoms for stabilization. |
Chemistry World April 28, 2014 Simon Hadlington |
Elusive sigma aromaticity captured Chemists in the US have created a unique transition metal hydride in which the hydrogens form a five-membered aromatic ring, something that had been theorized, but until now never seen. |
Chemistry World October 5, 2006 Mark Peplow |
Boron Shows Its Negative Side A molecule that hosts a negatively-charged boron atom could prove to be an exciting addition to the chemist's toolbox, according to researchers who have isolated the anion as its lithium salt. |
Chemistry World March 3, 2010 Jon Cartwright |
Hydrocarbon turns superconductor Researchers in Japan have created the first superconducting material based on a molecule of carbon and hydrogen atoms. |
Chemistry World March 19, 2009 Manisha Lalloo |
Copper catalysts give meta aromatics UK Researchers have discovered that, simply by using a copper catalyst, they are able to perform tricky substitution reactions at a difficult position on benzene rings |
Chemistry World April 7, 2014 Simon Hadlington |
Isolation of cyanoformate suggests new carbon capture approaches The formation of the cyanoformate ion helps to explain why plants' ethylene producing enzymes aren't poisoned by cyanide |
Chemistry World April 28, 2011 Simon Hadlington |
New method for aromatic coupling Chemists in Switzerland have developed a way to couple aromatic rings through the Friedel-Crafts mechanism - something many people would have believed impossible. |
Chemistry World January 24, 2010 Andy Extance |
Boron cluster forms unique ring system Clusters of nineteen boron atoms gather together in a ring structure unlike any other seen, with two planar -bonded aromatic systems nestled inside one another. |
Chemistry World August 14, 2012 Andy Extance |
Carbon clusters score lucky seven US and Chinese chemists say that they've calculated the structure of a stable carbon dication that would have a higher coordination number than any yet seen experimentally. |
Chemistry World February 6, 2012 David Bradley |
10 out of 10 for boron's coordinated effort A team in the US has created a boron compound that has the highest coordination number of any planar species, squeezing 10 spoke-like bonds from a central metal hub to 10 boron atoms equally spaced around a nanoscopic wheel. |
Chemistry World May 16, 2010 Simon Hadlington |
Anions enjoy a taste of pi European researchers have captured the moment when an anion interacts with the pi electron cloud of an aromatic molecule, something that has been known to occur but never seen at work. |
Chemistry World September 18, 2015 Tim Wogan |
Shining a light on amine synthesis A new method for site selective amination of aromatic organic compounds has been developed by researchers in the US. |
Chemistry World September 19, 2010 Simon Hadlington |
One dimensional carbon chains get longer Researchers in Canada have synthesised the longest polyyne to date - a linear chain of carbon atoms. |
Chemistry World December 19, 2010 Simon Hadlington |
Novel route to key aromatics US chemists have found a new way to create aromatic compounds from straight chains of hydrocarbons by using an iridium-based catalyst. |
Technology Research News August 11, 2004 |
Single gold atoms altered The gold atom, positioned on an ultrathin film of sodium chloride, remained stable during the operation, despite the change in charge. |
Chemistry World January 8, 2014 Caryl Richards |
First route to diphosphorus tetroxide Researchers from the University of Georgia, US, are the first to successfully synthesize stable diphosphorus tetroxide, the long sought-after phosphorus analogue of N 2O 4. What's more they performed the feat at room temperature. |
Reactive Reports Issue 63 David Bradley |
Natural Copy Cat While plants convert carbon dioxide into sugar and oxygen, chemists are having a more difficult time finding an efficient method for converting carbon dioxide into useful fuels. |
Technology Research News June 2, 2004 |
Buckyballs Gain Smaller Kin Researchers from Xiamen University and the Chinese Academy of Sciences have constructed a smaller version of the buckyball or C60 fullerene molecule, a spherical cage of carbon atoms. |
Chemistry World February 11, 2015 Jon Evans |
Calculations predict pentagonal graphene Scientists in China have proposed the existence of a novel 2D allotrope of carbon made up of pentagons, which they have dubbed 'penta-graphene'. |
Technology Research News August 13, 2003 |
Carbon wires expand nano toolkit Scientists looking for building blocks to form electronics and machines that are not much bigger than molecules have gained a new tool. |
Chemistry World November 2, 2015 |
Batzelladine B Of all the diverse substances that nature produces, the alkaloids -- small molecules containing basic nitrogen -- have had the greatest impact on human history and health. |
Chemistry World September 29, 2015 |
Navigating chemical space How big is chemistry? I don't mean how important is it, or how many people do it, but rather, how many molecules are there that we could make? |
Chemistry World December 6, 2007 Lewis Brindley |
Chemists Make Fullerene Necklace Spanish scientists have strung fullerene buckyballs together to produce a polymer with unique electronic properties. The creation of these polymers has demonstrated a new approach to designing novel materials. |
Chemistry World August 17, 2009 James Urquhart |
New method for fluorinating compounds Fluorine atoms are incorporated into aromatic organic compounds for many reasons, including their ability to increase metabolic stability, solubility and bioavailability. |
Chemistry World July 8, 2011 Mike Brown |
Pi-stacking better without the aromatics? Scientists in the US have discovered that electrons confined to their double bonds can sometimes deliver stronger pi-stacking interactions than those roaming free in aromatic systems. |
Chemistry World March 24, 2009 Karen Harries-Rees |
Alkali metals reveal a taste for clam Researchers have discovered a chemical curiosity, alkali metals that prefer aromatic surfaces to water and form clam-like structures. |
Chemistry World August 17, 2015 Jennifer Newton |
Molecular Sierpinski triangles get stability upgrade A team in China has constructed fractal triangles on the molecular scale and this time, they're much more robust. |
Technology Research News February 25, 2004 |
Nanotube mix makes liquid crystal Carbon nanotubes are rolled-up sheets of carbon atoms that can be as narrow as 0.4 nanometers, or the span of four hydrogen atoms. They have useful electrical and mechanical properties and are a leading player in nanotechnology. |
Chemistry World November 27, 2009 Simon Hadlington |
A simple way to join an olefin to an arene Chemists in the US have developed a simple and effective way to carry out a key class of reaction in organic synthesis - the bolting an olefin to an aromatic ring. |
Chemistry World November 28, 2012 Andrew Turley |
Lignin to lead bio-based chemicals? Lignin could come become the primary source of bio-based aromatic compounds for the chemical industry, according to a new report. |
Chemistry World April 21, 2011 James Urquhart |
Lignin cut down to size by nickel catalyst A nickel-based homogeneous catalyst that breaks down lignin - the tough polymer that forms plant cell walls - into useful building blocks suitable for chemicals, including green fuels, has been developed by US scientists. |
Chemistry World December 15, 2010 Hayley Birch |
New technique probes electron properties of individual atoms A new, low voltage electron microscopy technique allows scientists to discriminate not just between atoms of different elements but between atoms of the same element in different electronic states. |
Chemistry World January 28, 2015 |
Rubriflordilactone A It's likely that organic chemists have been practicing retrosynthesis in one form or another for at least a century, and certainly for decades before E J Corey formalized the concept in the mid-1990s |
Chemistry World February 28, 2008 James Mitchell Crow |
Chloride Ions in a Bind Chemists in the US have designed a donut-shaped molecule that tightly binds negatively-charged chloride ions. |