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Chemistry World
February 6, 2012
David Bradley
10 out of 10 for boron's coordinated effort A team in the US has created a boron compound that has the highest coordination number of any planar species, squeezing 10 spoke-like bonds from a central metal hub to 10 boron atoms equally spaced around a nanoscopic wheel. mark for My Articles similar articles
Chemistry World
July 14, 2014
Tim Wogan
First experimental evidence of a boron fullerene The first experimental evidence for a boron fullerene has been produced by researchers in the US and China. mark for My Articles similar articles
Chemistry World
April 28, 2014
Simon Hadlington
Elusive sigma aromaticity captured Chemists in the US have created a unique transition metal hydride in which the hydrogens form a five-membered aromatic ring, something that had been theorized, but until now never seen. mark for My Articles similar articles
Chemistry World
January 28, 2009
Manisha Lalloo
Ultra-pure boron structure discovered Scientists have characterised a new form of elemental boron - a notoriously hard element to synthesise in a pure form - and found that ionic bonding helps hold the structure together. mark for My Articles similar articles
Chemistry World
August 14, 2012
Andy Extance
Carbon clusters score lucky seven US and Chinese chemists say that they've calculated the structure of a stable carbon dication that would have a higher coordination number than any yet seen experimentally. mark for My Articles similar articles
Chemistry World
March 2, 2015
Andy Extance
Chemists zinc up 'aromatic' metal cubes Researchers in China and the US have synthesized polyzinc clusters that have pushed back the boundaries of the kind of aromatic structures chemists can make. mark for My Articles similar articles
Chemistry World
December 18, 2012
Caryl Richards
Boron vapor trail leads to heterofullerenes A team of scientists has developed a simple way to synthesize heterofullerenes -- fullerenes with atoms other than carbon in their structure -- by exposing fullerene to boron vapor during their growth. mark for My Articles similar articles
Chemistry World
January 19, 2007
Richard Van Noorden
Happy Families for Aluminium Chemists have discovered that aluminium - a notoriously anti-social element compared with its sister boron - may in fact form an unexpected family of hydride clusters. mark for My Articles similar articles
Chemistry World
July 8, 2010
Phillip Broadwith
Flattening carbon UK researchers have managed to synthesise a molecule with an almost planar four-coordinate carbon atom bonded to two lithium atoms and bulky organic ligands. mark for My Articles similar articles
Chemistry World
April 9, 2015
Simon Hadlington
Superatom mimics for rare earth elements Researchers in the US believe they may be able to create mimics of rare earth elements by making new 'superatoms' composed of atomic clusters of other metals. mark for My Articles similar articles
Chemistry World
July 27, 2015
Anisha Ratan
Boroles get a stability boost Scientists from Germany have reported a breakthrough in borole stability, using bulky fluoromesityl groups, which could help these anti-aromatic molecules realize their potential in optoelectronic devices. mark for My Articles similar articles
Chemistry World
July 7, 2014
Jennifer Newton
Buckyball boron Systematic structure-searching calculations performed by scientists in China have put forward an all-boron analogue of fullerene: B 38. mark for My Articles similar articles
Chemistry World
January 28, 2009
Phillip Broadwith
Water spilt with aluminium Aluminium clusters' ability to split water molecules and release hydrogen is dictated by the geometric arrangement of active sites on their surface, US scientists have discovered. mark for My Articles similar articles
Chemistry World
June 5, 2014
Jennifer Newton
Boron nitride Pringle predicted to be frequent flapper Researchers at the University of Nebraska-Lincoln, US, were so inspired after reading about the graphene Pringles reported last year that they decided to investigate equivalents made from boron and nitrogen. mark for My Articles similar articles
Wired
Erin Biba
Molecular Frameworks, the Building Blocks of All Life The world is complicated, but not as complicated as you might think. Most organic molecules derive from a few relatively simple architectures. mark for My Articles similar articles
Chemistry World
June 14, 2012
David Bradley
Tripling up on boron bonds Carbon and nitrogen are well known for their triple bonds, but making stable compounds with a triple bond between two boron atoms hadn't been achieved despite the computational possibilities. Until now. mark for My Articles similar articles
Chemistry World
January 19, 2011
Yuandi Li
Carbon dioxide clusters cracked by IR Canadian scientists have, for the first time, been able to identify spectroscopically carbon dioxide clusters that could provide valuable information on intermolecular interactions. mark for My Articles similar articles
Chemistry World
August 21, 2008
Fred Campbell
Double bonding with silicon In a landmark for silicon chemistry, US researchers have reported the first stable silicon (0) compound to contain a silicon-silicon double bond. mark for My Articles similar articles
Chemistry World
May 28, 2015
Matthew Gunther
Purely inorganic aromatic ion synthesized Scientists in the US have successfully synthesized an aromatic ion made from only nitrogen and phosphorus. The anion is a rare example of a stable aromatic species containing no carbon atoms. mark for My Articles similar articles
Chemistry World
April 19, 2007
Lewis Brindley
Superhard Material Made at Ambient Pressure Inorganic chemists in the U.S. have synthesized a material that rivals the hardness of diamond, without needing to use extremely high pressure. mark for My Articles similar articles
Chemistry World
November 12, 2015
Tim Wogan
Flat boron first looks promising for nano-electronics The super hard material, which was formed by two-stage chemical vapor deposition, has unusual properties for a two-dimensional material that could potentially make it very useful in nano-electronics. mark for My Articles similar articles
Chemistry World
January 29, 2010
Phillip Broadwith
Silicon goes aromatic Chemists in the UK have constructed a structural analogue of benzene made from silicon atoms. The molecule is not flat like benzene, but it reveals a new type of aromatic stabilisation. mark for My Articles similar articles
Chemistry World
October 5, 2006
Mark Peplow
Boron Shows Its Negative Side A molecule that hosts a negatively-charged boron atom could prove to be an exciting addition to the chemist's toolbox, according to researchers who have isolated the anion as its lithium salt. mark for My Articles similar articles
Chemistry World
February 11, 2015
Jon Evans
Calculations predict pentagonal graphene Scientists in China have proposed the existence of a novel 2D allotrope of carbon made up of pentagons, which they have dubbed 'penta-graphene'. mark for My Articles similar articles
Chemistry World
October 9, 2014
Katrina Kramer
Largest Mobius molecule synthesized Researchers from Korea and Japan have put a new twist on aromaticity, synthesizing the largest Mobius aromatic molecule to date. mark for My Articles similar articles
Chemistry World
May 16, 2006
Jon Evans
Buckyballs Worth Their Weight in Gold A team of chemists and physicists has uncovered evidence for the existence of hollow buckyball-like cages made of gold. mark for My Articles similar articles
Chemistry World
March 2010
Philip Ball
Column: The crucible Superatoms reinforce the notion that chemistry is more about electrons than elements, says the author mark for My Articles similar articles
Chemistry World
March 3, 2010
Jon Cartwright
Hydrocarbon turns superconductor Researchers in Japan have created the first superconducting material based on a molecule of carbon and hydrogen atoms. mark for My Articles similar articles
Chemistry World
March 2011
Column: The crucible Chemistry cannot all be reduced to physics, argues Philip Ball mark for My Articles similar articles
Chemistry World
April 15, 2010
Simon Hadlington
Lead joins the aromatic ring club Scientists in Japan have successfully incorporated an atom of lead into an aromatic molecule - the heaviest metal so far to be 'aromatised'. mark for My Articles similar articles
Chemistry World
December 10, 2014
Emma Stoye
Cutting edge chemistry in 2014 Highlights from last year's ground breaking chemical sciences research. mark for My Articles similar articles
Chemistry World
May 16, 2010
Simon Hadlington
Anions enjoy a taste of pi European researchers have captured the moment when an anion interacts with the pi electron cloud of an aromatic molecule, something that has been known to occur but never seen at work. mark for My Articles similar articles
Chemistry World
November 3, 2008
Simon Hadlington
Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple? mark for My Articles similar articles
Chemistry World
September 20, 2012
Jon Evans
World's smallest ice cube created Ice crystals must contain at least 275 water molecules, say German chemists. This size limit has implications for any process that involves ice particles, from cloud formation to making the perfect gin and tonic. mark for My Articles similar articles
Chemistry World
April 9, 2010
Mike Brown
Going for silver: green plastic production Scientists in the US have identified a new class of catalyst based on subnanometer clusters of three silver atoms that could provide a greener route to propylene oxide - a key intermediate used to make thousands of everyday products mark for My Articles similar articles
Chemistry World
January 31, 2014
Philip Ball
X-rays set to reveal electrons' dance In principle the very intense, ultra-short x-ray pulses produced by free-electron laser sources will be capable of revealing the motions of electrons in real time as they hop between different energy states in atoms and molecules. mark for My Articles similar articles
Chemistry World
March 19, 2009
Manisha Lalloo
Copper catalysts give meta aromatics UK Researchers have discovered that, simply by using a copper catalyst, they are able to perform tricky substitution reactions at a difficult position on benzene rings mark for My Articles similar articles
Chemistry World
September 6, 2007
Tom Westgate
Probe Maps Individual Atoms in Semiconductor Troublesome clusters of dopant atoms have been 'seen' for the first time. Researchers have drawn up the first 3D maps of the individual atoms in a semiconductor. mark for My Articles similar articles
Chemistry World
December 14, 2012
Jon Cartwright
Pico-gold clusters break catalysis record Chemists in Spain have shown that small clusters of gold atoms are excellent inorganic catalysts with record-breaking efficiency. mark for My Articles similar articles
Chemistry World
July 8, 2011
Mike Brown
Pi-stacking better without the aromatics? Scientists in the US have discovered that electrons confined to their double bonds can sometimes deliver stronger pi-stacking interactions than those roaming free in aromatic systems. mark for My Articles similar articles
Wired
October 2001
Wil McCarthy
Ultimate Alchemy Research into artificial atoms could lead to one startling endpoint: programmable matter that changes its makeup at the flip of a switch... mark for My Articles similar articles
Chemistry World
July 29, 2011
Simon Hadlington
Archetypal Lewis Acid Borane Turned Into a Base Chemists in the US and Germany have achieved the remarkable feat of transforming a borane, an archetypal electron-accepting Lewis acid, into an electron-donating Lewis base. mark for My Articles similar articles
Chemistry World
June 5, 2006
Simon Hadlington
The Attraction of Gold for Gold Researchers are unravelling some of the fundamental chemistry surrounding a key but poorly understood aspect of the coordination chemistry of gold -- the weak `aurophilic' interactions between adjacent atoms of Au(I) in organic complexes. mark for My Articles similar articles
Chemistry World
January 28, 2015
Rubriflordilactone A It's likely that organic chemists have been practicing retrosynthesis in one form or another for at least a century, and certainly for decades before E J Corey formalized the concept in the mid-1990s mark for My Articles similar articles
Chemistry World
February 28, 2007
Simon Hadlington
Individual Atoms' Chemical ID Revealed Researchers have demonstrated for the first time that atomic force microscopy can be used to reveal the chemical identity of individual atoms on a surface at room temperature. mark for My Articles similar articles
Technology Research News
May 4, 2005
Noisy Snapshots Show Quantum Weirdness Researchers have devised a relatively simple way to detect a pair of entangled, or linked atoms. The detection ability advances quantum computer and quantum communications research. mark for My Articles similar articles
Chemistry World
August 18, 2014
Laura Fisher
Radiolabels help evaluate emerging cancer treatment Researchers in Spain have come up with a way to track the biodistribution of a boron cluster complex used to prepare boron-carrier drugs for a prospective cancer treatment called boron neutron capture therapy. mark for My Articles similar articles
Chemistry World
July 20, 2009
Hayley Birch
Fuel cell catalysts go sub-nano Japanese researchers have created sub-nano scale platinum clusters with high catalytic activity for use in fuel cell applications. mark for My Articles similar articles
Chemistry World
July 29, 2013
Jennifer Newton
240 boron atoms in a single molecular species The unique supramolecular cuboctahedron contains 240 boron atoms and was synthesized by Chad Mirkin and colleagues at Northwestern University in Evanston, Illinois, via coordination-driven assembly. mark for My Articles similar articles
Chemistry World
April 28, 2011
Simon Hadlington
New method for aromatic coupling Chemists in Switzerland have developed a way to couple aromatic rings through the Friedel-Crafts mechanism - something many people would have believed impossible. mark for My Articles similar articles