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Chemistry World June 14, 2012 David Bradley |
Tripling up on boron bonds Carbon and nitrogen are well known for their triple bonds, but making stable compounds with a triple bond between two boron atoms hadn't been achieved despite the computational possibilities. Until now. |
Chemistry World June 28, 2013 Anthony King |
Titanium takes on Haber -- Bosch process The synthesis of ammonia under milder condition, using less energy and fewer resources, has moved a step closer. |
Chemistry World January 27, 2010 Phillip Broadwith |
Cracking carbon-carbon bonds Chemists in the US have discovered a tungsten complex that can break a strong carbon-carbon bond in an aromatic ring. |
Chemistry World September 19, 2014 Hugh Cowley |
Quintuple bond activates small stable molecules The activation of carbon dioxide, sulfur dioxide and nitrous oxide by a quintuply bonded dichromium complex has been reported by a team of researchers from Germany. |
Chemistry World August 23, 2007 James Mitchell Crow |
Tantalum Breaks Nitrogen Triple Bond Chemists have found a new way to tear apart the triple bond of dinitrogen - one of the strongest bonds there is - with a single atom. |
Chemistry World December 16, 2013 Tim Wogan |
Calculations predict stable eight nitrogen molecule Nitrogen could form an N 8 molecular crystal at low temperatures, according to density functional theory calculations done by Israeli and US researchers. |
Chemistry World September 24, 2009 Phillip Broadwith |
Carbon can't but tin can US chemists have discovered that distannynes - tin-based analogues of acetylenes - can react reversibly with ethene to make cyclic complexes. |
Chemistry World August 29, 2008 Fred Campbell |
Breaking the bonds of global warming US scientists have managed to prise apart the highly unreactive carbon-fluorine bond at room temperature, potentially paving the way to the efficient disposal of hydrofluorocarbons -- highly stable and long-lived greenhouse gases. |
Chemistry World June 23, 2011 Simon Hadlington |
Breaking the carbon-fluorine bond US chemists have discovered a new way to break the bond between carbon and fluorine atoms - the strongest carbon bond there is. |
Reactive Reports November 2007 David Bradley |
Organic Uranium The first ever uranium methylidyne molecule has been synthesized by US chemists despite the reactivity of the heavy, heavy metal. |
Chemistry World February 27, 2006 Katharine Sanderson |
Future Applications for CO Blue-Skies Surprise A catalytic system to turn carbon monoxide into fine-chemicals feedstocks could be developed within months, say researchers. The system would alleviate pressure on dwindling crude oil supplies, they predict. |
Chemistry World October 5, 2011 Simon Hadlington |
Turning Carbon Dioxide Into Chemicals with an Amine Chemists in France have devised a new way to turn carbon dioxide into a useful chemical building block. |
Chemistry World November 10, 2011 David Bradley |
A soluble solution to the Haber process? A clearer understanding of the activity of the key component of the Haber-Bosch process - the catalyst - could help to optimize industrial nitrogen fixation still further and remove the need for high temperatures and pressures. |
Chemistry World November 2010 |
Carbon Couplers Take the Prize Three giants of organic chemistry, who pioneered palladium-catalysed cross coupling reactions, have shared this year's Nobel prize. |
Chemistry World April 14, 2009 Lewis Brindley |
Osmium and pyridine ring together Organic chemists in China have found a way to put osmium into a pyridine ring - leading to the synthesis of the first metallapyridinium complex. |
Chemistry World March 21, 2007 Richard Van Noorden |
Forcing a Reaction US chemists have forced molecules to react by ripping their bonds apart with ultrasound. The scientists carefully stretched one targeted bond until it snapped, guiding the molecule's subsequent reaction into pathways forbidden by conventional chemistry. |
Chemistry World September 4, 2013 Mark Peplow |
Iron catalyst offers nitrogenase clues It is one of the most enduring mysteries in chemistry: how do certain bacteria fix nitrogen from the air? |
Chemistry World March 25, 2012 Phillip Broadwith |
Germanium-Oxygen Double Bond Takes Centre Stage The first compound with a germanium-oxygen double bond has been created by Japanese scientists. |
Chemistry World August 16, 2009 Tom Bond |
Catalyst free carbon-carbon bond formation The method offers an environmentally friendly way to form one of the most important bonds in organic synthesis. |
Chemistry World May 29, 2015 Derek Lowe |
Magic molecule modifiers The synthesis of a new organic molecule can be approached in several ways. |
Chemistry World October 2007 Bernard Bulkin |
Can Chemistry Save the Planet? If we are to scale back our greenhouse gas emissions without society juddering to a halt, 21st century transport will need 21st century fuels. And of all the sciences, it is chemistry that is best placed to deliver them. |
Chemistry World May 7, 2008 Lewis Brindley |
Super-sized molecular sponges boost carbon capture Super-sized molecular sponges that trap and store carbon dioxide have been unveiled by chemists in the US. |
Chemistry World February 21, 2007 Tom Westgate |
Complex Organic Molecules Teamed with Iodine Chemists have developed a method for constructing complex halogen-containing organic molecules from simple compounds in a single step. The discovery could pave the way for the synthesis of many potentially useful naturally occurring molecules. |
Chemistry World January 29, 2012 Andy Extance |
Calculations reveal carbon-carbon quadruple bond C 2's two carbon atoms aren't joined by a double bond as usually thought, or even a triple bond, but in fact a quadruple bond. |
Chemistry World August 5, 2010 Simon Hadlington |
Nitrogenase found to be a two-trick pony An enzyme whose job is to convert nitrogen gas to ammonia - a process known as nitrogen fixation - can also reduce carbon monoxide US researchers have discovered. |
Chemistry World August 21, 2008 Fred Campbell |
Double bonding with silicon In a landmark for silicon chemistry, US researchers have reported the first stable silicon (0) compound to contain a silicon-silicon double bond. |
Chemistry World November 3, 2008 Simon Hadlington |
Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple? |
Chemistry World April 30, 2015 Rebecca Trager |
Anton Toutov: The power of potassium Toutov says the potassium catalyst he has developed costs only about $30 per mole, or less. 'It is safer and non-toxic, and a lot more cost-effective,' he states. |
Reactive Reports Issue 63 David Bradley |
Natural Copy Cat While plants convert carbon dioxide into sugar and oxygen, chemists are having a more difficult time finding an efficient method for converting carbon dioxide into useful fuels. |
Chemistry World January 16, 2013 Simon Hadlington |
Azo-cops nab CO 2 but let N 2 go free Scientists have developed a new class of porous polymer that can efficiently trap carbon dioxide while actively rejecting nitrogen. |
Chemistry World July 13, 2015 Philip Ball |
First snapshot of elusive intermediate supplies surprise A team near Zurich in Switzerland, has been able to take a single-molecule snapshot of an intermediate in a common class of organic reactions. |
Chemistry World March 9, 2006 Katharine Sanderson |
Covalent Bonds Crack Under the Strain Chemists must consider engineering principles when designing molecules following news that tough carbon-to-carbon bonds break easily under mechanical strain. |
Chemistry World October 8, 2015 Andy Extance |
Chemists harness impermanent 'star' molecule Thirty-eight years after the last member of the [n]radialene class of star-shaped hydrocarbons was first reported, chemists have made its missing member. |
Chemistry World May 13, 2013 Philip Ball |
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? |
Chemistry World January 29, 2015 Santiago Alvarez |
What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept. |
Chemistry World September 12, 2013 Andy Extance |
Sulfur difluoride dimer exposes bonding strangeness Calculations on unusual bonding in the sulfur difluoride dimer FSSF 3 have provided evidence to help explain why some compounds don't follow long-established chemical rules. |
Chemistry World February 2011 |
Rehabilitating captured CO2 Rather than burying it underground, companies are developing processes that use carbon dioxide emissions as chemical starting materials. Andy Extance investigates |
Chemistry World December 21, 2011 James Urquhart |
For clean carbon dioxide conversion just add water Japanese researchers have shown that photocatalytic reduction of CO 2 is possible using water as the reducing agent. |
Chemistry World March 29, 2012 Simon Hadlington |
Seeds of life incubated in proto-planetary nurseries New findings imply that the organic chemistry required to produce the necessary molecules for life is part of the normal processes of planet formation. |
Chemistry World June 2008 Sarah Houlton |
Breaking the rules The author finds out about some chemical tricks that can give a new drug the best possible odds of success |
Chemistry World January 25, 2007 Richard Van Noorden |
Water Surprise for Atmospheric Scientists Lone water molecules can catalyze reactions between atmospheric gases, scientists have confirmed, throwing a wrench in the works of supposedly simple atmospheric chemistry. |
Chemistry World June 23, 2015 Matthew Gunther |
Photo-catalysts shine light on chemical bond making A team of scientists from Israel and Germany have manipulated bond formation in a chemical reaction using high power lasers |
Chemistry World April 25, 2014 Derek Lowe |
Engineering serendipity At this stage in the world of organic chemistry, you'd have to think that many of the great reactions that can be stumbled across with known reagents have probably been found. |
Chemistry World October 26, 2006 Victoria Gill |
Volcanoes Reveal the Secret of the Origin of Life Life began with a chemical reaction under the sea over four billion years ago. That is the claim of a German scientist whose team has recreated a crucial part of the reaction, synthesizing all the necessary ingredients for a living organism. |
Chemistry World May 23, 2011 Simon Hadlington |
Homing in on a cheaper Haber-Bosch process A cheaper alternative to the Haber-Bosch process could have moved a step closer thanks to a new ruthenium-based catalyst complex developed by chemists in Germany. |
Reactive Reports November 2007 David Bradley |
Cats Don't Work Like That Scientists have discovered that the three-way catalytic converter in your car converts carbon monoxide into carbon dioxide in two reaction steps, instead of a single step as previously thought. |
Chemistry World September 26, 2013 Akshat Rathi |
First pictures of hydrogen bonds unveiled Researchers in China report the first visualization of a hydrogen bond using atomic force microscopy. |
Chemistry World June 18, 2013 Rowan Frame |
Hydrogen generation using sunlight Scientists from Spain have found a catalyst that can use sunlight to power an important industrial reaction for the production of hydrogen at ambient temperatures. |
Chemistry World March 2012 |
Column: In the pipeline Drug discovery requires experimentation, says Derek Lowe. But chemists can be reluctant to stray from the elements they know and love |
Chemistry World December 3, 2009 Simon Hadlington |
C-H Bond Activation Takes the Relaxing Route Chemists have uncovered a key factor that helps determine the reactivity of a C-H bond to oxidation. |