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Chemistry World October 11, 2013 Andy Extance |
'Tetrel bonding' emerges from I -hole Researchers have coined the term 'tetrel bonding' to highlight little-studied but powerful non-covalent bonding between electron donors and the group 14 elements, silicon, germanium and tin. |
Chemistry World May 29, 2015 Andy Extance |
Noble gas joins I -hole interaction crowd Despite noble gases' characteristic unreactivity, Spanish chemists have calculated that molecules containing xenon can interact non-covalently through what they've called 'aerogen bonding'. |
Chemistry World October 3, 2014 Jennifer Newton |
Assessing covalency in the hydrogen bond zoo Worried that the concept of hydrogen bonding has been getting fuzzier over time, scientists in Germany have sought a fresh look at the very nature of these bonds, and how much covalency they involve. |
Chemistry World January 29, 2015 Santiago Alvarez |
What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept. |
Chemistry World February 18, 2011 Carol Stanier |
Speed dating for pharmaceuticals A simple analysis of hydrogen bond strengths finds the best crystallisation partners for drugs, say UK scientists. |
Chemistry World November 3, 2010 Andy Extance |
Hydrogen bond set to be redefined The world authority on chemical nomenclature is preparing to scrap the familiar hydrogen bond definition, in light of recent evidence about its true nature. |
Chemistry World March 25, 2013 David Bradley |
Hydrogen bond under the microscope Scientists in Japan have designed a scanning tunnelling microscope tip that allowed them to measure electron transfer across a single hydrogen bond. |
Chemistry World December 4, 2006 Richard Van Noorden |
Hydrogen Gets Promiscuous Hydrogen is a more promiscuous element than chemists have appreciated: it can form up to six strong chemical bonds in some solids, researchers report. |
Chemistry World March 24, 2009 Karen Harries-Rees |
Alkali metals reveal a taste for clam Researchers have discovered a chemical curiosity, alkali metals that prefer aromatic surfaces to water and form clam-like structures. |
Chemistry World December 10, 2014 Jason Woolford |
I meets I for a hole lot of bonding Researchers in India have provided experimental verification that a co-operative I -hole and I -hole are responsible for holding the molecules of an isothiocyanate based peptide together in its crystal lattice. |
Chemistry World November 10, 2014 Andy Extance |
Hydrogen bond pictures come under close scrutiny Scientists have cast doubt on whether striking atomic force microscopy images previously thought to show hydrogen bonds are real or merely an artefact. |
Chemistry World June 14, 2012 David Bradley |
Tripling up on boron bonds Carbon and nitrogen are well known for their triple bonds, but making stable compounds with a triple bond between two boron atoms hadn't been achieved despite the computational possibilities. Until now. |
Chemistry World August 21, 2008 Fred Campbell |
Double bonding with silicon In a landmark for silicon chemistry, US researchers have reported the first stable silicon (0) compound to contain a silicon-silicon double bond. |
Chemistry World May 13, 2013 Philip Ball |
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? |
Chemistry World September 14, 2011 Laura Howes |
Aspirin Still Has Some Secrets Left to Give up The overlooked stereoelectric effect in aspirin makes the molecule less polar, which may improve the drug's bioavailability. |
Technology Research News August 13, 2003 |
Carbon wires expand nano toolkit Scientists looking for building blocks to form electronics and machines that are not much bigger than molecules have gained a new tool. |
Chemistry World May 21, 2010 Simon Hadlington |
H-bond partner-swapping seen in the flesh The dance moves that a water molecule makes as it flips hydrogen bonds from one partner to another have been captured by US researchers. |
Chemistry World September 26, 2013 Akshat Rathi |
First pictures of hydrogen bonds unveiled Researchers in China report the first visualization of a hydrogen bond using atomic force microscopy. |
Technology Research News November 17, 2004 |
Low-Pressure Material Holds Hydrogen One key to using hydrogen as a fuel is finding practical ways to store it. Researchers have discovered a kinetic trapping effect that allows hydrogen to be adsorbed. |
Chemistry World March 27, 2012 Erica Wise |
Unlocking the mysteries of ice The unusual properties of ice under compression are due to Coulomb repulsion between bonding and non-bonding electron pairs, say scientists from Singapore and China. |
Chemistry World September 3, 2008 Lewis Brindley |
Hydroxide argument settled Scientists in Germany say they have settled an argument over how hydroxide ions travel quite so quickly through water, after finding evidence that they can donate a weak hydrogen bond. |
Chemistry World April 11, 2010 Simon Hadlington |
Phosphorus fragments trapped Researchers in the US and Germany have shown how a rare and highly reactive form of phosphorus can be captured and crystallised, making it stable even at room temperature. |
Chemistry World March 2011 |
Column: The crucible Chemistry cannot all be reduced to physics, argues Philip Ball |
Chemistry World December 15, 2010 Hayley Birch |
New technique probes electron properties of individual atoms A new, low voltage electron microscopy technique allows scientists to discriminate not just between atoms of different elements but between atoms of the same element in different electronic states. |
Chemistry World January 20, 2010 James Urquhart |
Disilicate synthesis success A compound containing a stable silicon-silicon bond between two negatively charged pentacoordinated silicon atoms - silicates - has been synthesized and isolated for the first time by Japanese researchers. |
Chemistry World May 8, 2013 Cara E Sutton |
Coming unstuck with DNA A DNA-based glue has been developed by scientists at the University of Illinois, US. The adhesive uses DNA base pair mimics that bind to each other more strongly than their natural counterparts and may lead to glues far more powerful than Super Glue. |
Chemistry World November 3, 2015 Matthew Gunther |
IR spectroscopy stretches knowledge of hydrogen bonding Scientists in Denmark have, for the first time, detected a hydrogen bond between an N -- H and phosphorus in the gas phase. |
Chemistry World September 4, 2015 Hugh Cowley |
Hypervalent bonding controversy out for the electron count? A researcher in the UK has presented a controversial new definition for hypervalency that may ignite debates over atomic charge and allow students to draw nitrogen atoms with five covalent bonds. |
Chemistry World February 12, 2013 Philip Ball |
Water structure controversy laid to rest? A controversy about the structure of liquid water that has raged for almost a decade may be laid to rest by a new computational study. |
Chemistry World November 7, 2013 Polly Wilson |
Hydrogen adopts alkali metal position For the first time, scientists have shown that hydrogen can stand in for alkali metals in typical alkali metal structures. |
Chemistry World May 16, 2010 Simon Hadlington |
Anions enjoy a taste of pi European researchers have captured the moment when an anion interacts with the pi electron cloud of an aromatic molecule, something that has been known to occur but never seen at work. |
Chemistry World January 28, 2009 Phillip Broadwith |
Water spilt with aluminium Aluminium clusters' ability to split water molecules and release hydrogen is dictated by the geometric arrangement of active sites on their surface, US scientists have discovered. |
Chemistry World April 28, 2014 Hamish Crawford |
Crystal structures unpacked A researcher in the UK has shed new light on which interactions are important in the packing of crystal structures. |
Chemistry World October 10, 2014 Laura Fisher |
Dangling bonds induce ferromagnetism in graphitic carbon nitride Researchers have achieved ferromagnetism in graphitic carbon nitride, g-C 3N 4, by introducing hydrogen dangling bonds into its two-dimensional structure, making the material suitable for spintronic devices. |
Reactive Reports Issue 54 David Bradley |
Metals Take on Carbon's Bonding Characteristics A rethink about chemical bonding might be in the cards thanks to research that shows that the metal indium forms bonds in a manner not dissimilar to organic carbon atoms. |
Reactive Reports Issue 31 David Bradley |
Ammonia for the primordial brew A newly discovered nitrogen-fixation reaction may have played a role in the emergence of life, according to German researchers. |
Chemistry World July 16, 2009 Simon Hadlington |
Strange vibrations Researchers in Taiwan have shown that in a relatively simple molecular system the induced vibrations can inhibit the breaking of the bond and slow the reaction down. |
Chemistry World November 5, 2007 Ned Stafford |
Joining up Nanocircuits A team of scientists have covalently bonded strings of porphyrin molecules on a gold surface -- a step forward in the quest to develop nano-electronics. |
Chemistry World June 5, 2006 Simon Hadlington |
The Attraction of Gold for Gold Researchers are unravelling some of the fundamental chemistry surrounding a key but poorly understood aspect of the coordination chemistry of gold -- the weak `aurophilic' interactions between adjacent atoms of Au(I) in organic complexes. |
Chemistry World May 27, 2014 Simon Hadlington |
Unusual H-bond patterns revealed in single molecule image Researchers in the US have used a scanning tunnelling microscope to produce the latest images of structure and bonding in a single molecule, by sensing the molecule's local potential energy landscape. |
Technology Research News December 15, 2004 Kimberly Patch |
Molecule Harvests Water's Hydrogen The key to producing clean hydrogen energy is finding a non-polluting method to extract pure hydrogen from its most abundant source, water. Researchers have developed a supramolecular complex that could be used in devices that use light energy to extract hydrogen from water. |
Technology Research News September 24, 2003 |
Artificial DNA stacks metal atoms In recent years, researchers have replaced some of DNA's natural bases with those that attach to metal atoms in order to coax DNA to organize metal ions into tiny structures. Researchers in Japan have tapped the method to form stacks of single metal ions. |
Chemistry World June 9, 2009 Simon Hadlington |
Super sponges soak up gas Researchers in the US have shown that a recently discovered class of compound based on light elements can store gas at least as efficiently as the most promising metal organic framework candidates. |
Chemistry World November 22, 2009 Lewis Brindley |
Bonding under pressure An unusual compound of xenon and hydrogen has been made under high pressure by researchers in the US. |
Chemistry World February 28, 2008 James Mitchell Crow |
Chloride Ions in a Bind Chemists in the US have designed a donut-shaped molecule that tightly binds negatively-charged chloride ions. |
Technology Research News June 4, 2003 |
Study shows DNA will fill tubes Researchers from the Max Planck Institute in Germany have shown by computer simulation that it is possible to insert DNA into a carbon nanotube. |
Chemistry World January 8, 2014 Philip Ball |
We choose to go to the muon Chemists Mohammad Goli and Shant Shahbazian posit two new light elements. They are muonium (Mu), in which an electron orbits a positively charged muon ( +), and muonic helium (He ), in which an electron orbits a 'nucleus' consisting of an alpha particle and a negative muon. |
Chemistry World April 29, 2009 Matt Wilkinson |
World's first 'naked' uranium-transition metal bond formed UK scientists have made 'naked' uranium-transition metal bonds, providing vital evidence that valence orbitals can play a role in actinide bonding. |
Chemistry World June 23, 2011 Simon Hadlington |
Breaking the carbon-fluorine bond US chemists have discovered a new way to break the bond between carbon and fluorine atoms - the strongest carbon bond there is. |
Chemistry World June 25, 2014 Tim Wogan |
Unusual 2D silica allotrope predicted A graphene-like allotrope of silica with unusual physical and electrical properties has been predicted by theoretical chemists in Turkey. |