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Chemistry World
November 17, 2008
Simon Hadlington
Catalyst flexes for extra control US chemists have developed a new type of catalyst capable of exerting high stereochemical control over olefin metathesis reactions mark for My Articles similar articles
Chemistry World
July 26, 2007
Tom Westgate
Counterion Does the Twist US chemists have achieved a breakthrough in the design of catalysts that selectively produce chiral compounds. mark for My Articles similar articles
Chemistry World
May 30, 2013
Andy Extance
Catalyst duo exerts powerful stereocontrol Chemists from the Swiss Federal Institute of Technology, ETH Zurich, have teamed chiral catalysts in pairs to selectively drive a reaction towards desired stereoisomeric products with high selectivity. mark for My Articles similar articles
Chemistry World
May 9, 2010
Phillip Broadwith
Iron catalyst breaks the mold An iron catalyst that is not only greener than many of its precious metal competitors, but also catalyses reactions that they can't, could open new avenues in transition metal catalysis, say Chinese researchers. mark for My Articles similar articles
Chemistry World
June 10, 2010
Phillip Broadwith
A green and salty chiral catalyst An efficient, chiral, salt-based hypervalent iodine catalyst has been discovered by Japanese chemists that could replace toxic metal catalysts without generating the waste or explosion risks associated with hypervalent organo-iodine complexes. mark for My Articles similar articles
Chemistry World
April 11, 2011
Mike Brown
One catalyst, two reactions Researchers in the US have designed a novel material that can catalyse two separate, sequential reactions to produce industrially relevant intermediates in one pot. mark for My Articles similar articles
Chemistry World
December 17, 2009
Simon Hadlington
Single catalyst gives two products from racemic mixture Chemists in the US have demonstrated a remarkable reaction in which a single catalyst can transform a racemic mixture - molecules identical in every way except for their chirality - into two distinct enantiomerically pure products. mark for My Articles similar articles
Chemistry World
September 4, 2008
Fred Campbell
Two catalysts better than one US researchers have cracked a long standing problem in chemical synthesis - the catalytic alpha-alkylation of aldehydes - by combining two catalysts in one pot. mark for My Articles similar articles
Chemistry World
October 18, 2011
Steve Down
Cofactor Control of Catalysis Enantioselectivity Scientists have used cofactors to control the enantioselectivity of supramolecular transition metal catalysts, enabling the asymmetric hydrogenation of a series of acrylates and related compounds with remarkably high selectivities. mark for My Articles similar articles
Chemistry World
June 27, 2013
Emma Eley
Sustainable iron catalyst for clean hydrogenation An international team of chemists has reported a clean and green way to perform one of the most important industrial reactions for pharmaceutical and petrochemical synthesis. mark for My Articles similar articles
Chemistry World
February 21, 2008
Lewis Brindley
Esters Made Easy with Indium Indium is the basis of a novel catalyst designed to make useful cyclic esters. This catalyst could greatly simplify the production of chiral dihydropyranones, important structural elements in many natural products and pharmaceuticals. mark for My Articles similar articles
Chemistry World
April 6, 2009
Nina Notman
Torn catalysts help polymers heal themselves Catalysts that are activated by a mechanical force tearing them in two have been designed by Dutch scientists. mark for My Articles similar articles
Chemistry World
June 1, 2006
Michael Gross
New Twists on Catalysis Chemists around the world have discovered several new twists to improve the performance of asymmetric catalysts in hydrogenation reactions. mark for My Articles similar articles
Chemistry World
November 28, 2013
Andy Extance
Base metal catalysts strike hydrogenation gold Three teams have shown that chemists need not rely only on expensive and toxic precious metal catalysts for hydrogenation -- they've found complementary alternatives based on cheap, abundant and safer transition metals. mark for My Articles similar articles
Chemistry World
May 15, 2014
Jenifer Mizen
Freeze-dried cells make better biocatalysts A biocatalytic cascade using mashed-up cells has overcome extraction and solubility problems associated with using enzymes in chemical syntheses. mark for My Articles similar articles
Chemistry World
April 18, 2012
Elinor Richards
Homogeneous Catalyst Recovery Made Easier Scientists have now found a way to recover homogeneous catalysts at the end of a chemical reaction that doesn't suffer from the slow reaction rates that affect current catalyst recovery systems. mark for My Articles similar articles
Chemistry World
September 9, 2011
James Mitchell Crow
High-throughput catalyst screening for the masses Using nothing more than the standard chemistry lab equipment, researchers in the US have successfully turned the discovery of new catalytic reactions into a high-throughput process. mark for My Articles similar articles
Chemistry World
July 16, 2013
Harriet Brewerton
Accelerating stereochemical analysis A chemosensor has been developed by scientists in the US to speed up the quantitative stereochemical analysis of chiral amino alcohols and diamines. mark for My Articles similar articles
Chemistry World
March 20, 2008
James Mitchell Crow
Surfactants Help Reactions Work in Water Scientists have discovered a surfactant that allows the catalytic organic reactions commonly used to assemble organic structures such as drug molecules to be run in water. mark for My Articles similar articles
Chemistry World
January 6, 2010
Phillip Broadwith
Enzymes do the twist The way enzyme catalysts bind molecules to speed up their reactions is not as simple as once thought, say chemists from the UK and Spain. mark for My Articles similar articles
Chemistry World
November 3, 2014
Debbie Houghton
Engineered metalloenzyme catalyses Friedel -- Crafts reaction Reprogramming the genetic code of bacteria to incorporate an unnatural amino acid has allowed scientists in the Netherlands to create a new metalloenzyme capable of catalyzing an enantioselective reaction. mark for My Articles similar articles
Chemistry World
February 11, 2008
Lewis Brindley
Oxidation Goes Green A new 'green' strategy for making useful nitrogen-based chemicals has been announced by chemists in the UK. mark for My Articles similar articles
Chemistry World
December 3, 2014
Cally Haynes
One rotaxane, two catalytic stories A two-site supramolecular catalyst that can be programmed to mediate different reactions depending on its conformation has been designed by researchers in the UK. mark for My Articles similar articles
Chemistry World
December 5, 2012
Phillip Broadwith
Chemical reactions in hot water Chinese and Japanese chemists have highlighted hot water's ability to promote unexpected reactions without any other reagents or catalysts. The work should expand our understanding of how to harness the physicochemical properties of water to potentially replace more complex reagents and catalysts. mark for My Articles similar articles
Chemistry World
November 26, 2012
Laura Howes
Protein coat prepares catalyst for cascades By protecting a transition metal catalyst with a protein coat, scientists have managed to couple up biocatalysts and chemical catalysts to perform a cascade reaction. mark for My Articles similar articles
Chemistry World
August 16, 2009
Tom Bond
Catalyst free carbon-carbon bond formation The method offers an environmentally friendly way to form one of the most important bonds in organic synthesis. mark for My Articles similar articles
Chemistry World
April 10, 2008
Mark Peplow
'Pot-in-a-Pot' Technique Makes Impossible Cascade Reactions Easy A simple technique that nests a series of reaction vessels could help chemists avoid the tedium and expense of purifying organic compounds after each step of a long synthesis. mark for My Articles similar articles
Chemistry World
April 4, 2008
James Mitchell Crow
More to Catalysis Than Meets the Eye Catalysts are more than just a reactive surface. Changes beneath a metal's skin can completely change the course of a reaction. mark for My Articles similar articles
Chemistry World
December 23, 2015
Karl Collins
Scratching chiral surfaces There are numerous challenges to developing reactions that exploit chiral surfaces, or employ molecular modifiers (ligands) to create a chiral surface environment and control the stereoselectivity of a transformation. mark for My Articles similar articles
Chemistry World
February 6, 2011
Laura Howes
Cells as test tubes Chemists have used living cells as test tubes to carry out chemical reactions never before seen within living cells. mark for My Articles similar articles
Chemistry World
September 22, 2015
Andy Extance
Firming COFs up takes Michael reaction catalysis forward By making formerly fragile covalent organic frameworks resistant to harsh conditions, researchers have created what they think could be a powerful new catalyst concept. mark for My Articles similar articles
Chemistry World
April 25, 2010
Hayley Birch
New strategy yields best ever catalyst for ammonia decomposition US researchers have developed a new strategy for predicting bimetallic catalysts. mark for My Articles similar articles
Chemistry World
September 20, 2007
Lewis Brindley
New Catalyst Rings the Changes Organic chemists in the US have developed a method to control the stereochemistry of a useful intramolecular Diels-Alder reaction. mark for My Articles similar articles
Chemistry World
March 25, 2011
Simon Hadlington
New synthesis for chiral anticancer compound The promising anticancer compound nutlin-3 is likely to become more widely available to researchers thanks to a new synthetic protocol developed by US chemists. mark for My Articles similar articles
Chemistry World
March 8, 2011
Jon Cartwright
Carbon nanotubes - a boon for chiral catalysts Researchers in China have created a new catalyst that could help in the production of chiral molecules for medical drugs. The catalyst, which consists of platinum nanoparticles encapsulated in carbon nanotubes, is the most active of its type ever reported. mark for My Articles similar articles
Chemistry World
September 21, 2009
Hayley Birch
Enzymes inspire new catalyst design for hydrogen production A novel enzyme-based catalyst developed by UK and US researchers hints at new ways of designing catalysts for the water-gas shift reaction, an important industrial reaction in the production of high grade hydrogen. mark for My Articles similar articles
Chemistry World
November 7, 2014
Katrina Kramer
Stressed ligands switch catalysis selectivity Researchers have discovered that enantioselectivity in palladium-catalyzed reactions depends on the ligand's intramolecular strain. mark for My Articles similar articles
Chemistry World
January 7, 2010
Lewis Brindley
Upgrading biomass to gasoline Making cheap gasoline from biomass is a step closer, thanks to a new catalyst developed in the US. mark for My Articles similar articles
Chemistry World
November 12, 2008
Lewis Brindley
Microscope Reveals Catalyst Secrets A promising technique for watching catalysts in action could provide new insights into how they work, report scientists in the Netherlands. mark for My Articles similar articles
Chemistry World
December 3, 2009
Hayley Birch
Bio-Inspired Catalyst Design Could Rival Platinum French scientists have demonstrated the potential of a new fuel cell catalyst inspired by hydrogenase enzymes. mark for My Articles similar articles
Chemistry World
April 19, 2009
Hayley Birch
Chiral metals shape up for catalysis Dutch and Israeli scientists have found a way to induce the chirality usually only found in organic materials in palladium. mark for My Articles similar articles
Chemistry World
September 6, 2006
Michael Gross
Selective Shortcut Chemists have developed a simple catalyst that speeds up the synthesis of a chiral protected building block used in many complex syntheses. mark for My Articles similar articles
Chemistry World
February 20, 2012
James Urquhart
Unusual kinetics of catalyst revealed US researchers have elucidated the unusual reaction kinetics of C-H activation by the palladium(II) catalyst (Pd(OAc) 2). mark for My Articles similar articles
Chemistry World
December 12, 2007
Jonathan Edwards
Aqueous Fischer-Tropsch is Clean and Green Chinese chemists have carried out the Fischer-Tropsch reaction in water for the first time, bringing a greener route to hydrocarbon fuels a step closer. mark for My Articles similar articles
Chemistry World
July 15, 2010
Simon Hadlington
Synthetic enzyme catalyses Diels-Alder reaction The reaction is key to many organic syntheses and suggests that artificial enzymes could soon become part of the synthetic chemist's toolkit. mark for My Articles similar articles
Chemistry World
February 19, 2010
Simon Hadlington
Forcing stereoselectivity on reactive cations Chemists in the US have devised a dual catalyst strategy to tame the highly reactive iminium ion to give a high degree of stereochemical control over subsequent reactions of the ion. mark for My Articles similar articles
Chemistry World
December 4, 2009
James Urquhart
Easier ester synthesis Researchers in the US have shown how oxygen-coated gold nanoparticles can selectively oxidise a variety of alcohols and aldehydes. mark for My Articles similar articles
Chemistry World
December 3, 2010
Elinor Richards
Graphene catalyst comes out on top Sulfonated graphene solid acid catalysts could be cheap, environmentally friendly alternatives to concentrated sulfuric acid for use in industry because they can be recycled, say scientists from China. mark for My Articles similar articles
Chemistry World
January 25, 2013
Derek Lowe
Name reactions: how does the label stick? Some of these names go back to the 19th century, and many more of them come from the first decades of the 20th. Once in a while, I wonder if the tradition is dying out. Are we still naming chemical reactions after their discoverers? mark for My Articles similar articles
Chemistry World
October 30, 2007
James Mitchell Crow
A Better Catalyst for Fuel Cells? Alloy nanoparticles that efficiently catalyse oxygen's conversion into water - the energy-releasing reaction that occurs in fuel cells - have been discovered. The particles are up to six times more active than pure platinum, the material typically used in current fuel cells. mark for My Articles similar articles