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Chemistry World
June 5, 2012
Simon Perks
Chiral separation with micro-flows How do you separate enantiomers without any kind of chiral recognition between molecules? The answer it seems is to use asymmetric flow in a micro-fluidic channel. mark for My Articles similar articles
Chemistry World
May 15, 2012
Harriet Brewerton
Chiral Confusion Scientists in Israel have shown that non-biological chiral crystals are much more abundant than previously thought and their findings could clear up a possible confusion over the term 'chiral'. mark for My Articles similar articles
Reactive Reports
May 2007
David Bradley
Meeting of Molecular Movie Stars New footage confirms Linus Pauling's theory of chemical bonding proposed half a century ago, and could help explain molecular recognition processes important throughout supramolecular chemistry and molecular biology. mark for My Articles similar articles
Chemistry World
June 25, 2012
Michael Gross
Running Rings Around Molecular Wires New research could open up the possibility of using new carbon compounds as wires in molecular electronics. mark for My Articles similar articles
Chemistry World
April 19, 2009
Hayley Birch
Chiral metals shape up for catalysis Dutch and Israeli scientists have found a way to induce the chirality usually only found in organic materials in palladium. mark for My Articles similar articles
Chemistry World
March 2, 2007
Philip Ball
Giving Life a Hand Why are proteins left-handed and nucleic acids right-handed? Once offered only a few sketchy theories, scientists have found more alternatives for creating homochirality. mark for My Articles similar articles
Chemistry World
July 16, 2013
Harriet Brewerton
Accelerating stereochemical analysis A chemosensor has been developed by scientists in the US to speed up the quantitative stereochemical analysis of chiral amino alcohols and diamines. mark for My Articles similar articles
Chemistry World
November 17, 2015
Matthew Gunther
Rotaxane raises the bar for self-replicating chemical systems Scientists in the UK and Malaysia have created a self-assembling rotaxane that can replicate itself. The result may lead to the development of autonomous chemical systems that mimic cellular processes. mark for My Articles similar articles
Chemistry World
September 26, 2014
Jennifer Newton
James Crowley: Magicians rings and dumbbells on a molecular scale Research in Crowley's group combines synthetic organic, inorganic, organometallic and supramolecular chemistry to design and synthesize new functional materials. mark for My Articles similar articles
Chemistry World
November 3, 2011
Erica Wise
A Model for the Single Chirality of Life The boiling solutions in prebiotic hot springs could shed light on the emergence of a single chiral form of biomolecules in nature, say Spanish scientists. mark for My Articles similar articles
Chemistry World
January 6, 2015
Jennifer Newton
Light drives unusual rotaxane-to-catenane transformation Researchers in Europe have reported a mechanically-interlocked molecular system that can reversibly switch between being a rotaxane and a catenane. mark for My Articles similar articles
Chemistry World
August 7, 2011
Phillip Broadwith
Possible Origin of Chirality in the Rna World Given a tiny push one way or the other, simple racemic precursors can lead to the chiral building blocks of RNA using a combination of chemical and physical factors. mark for My Articles similar articles
Chemistry World
March 28, 2007
Victoria Gill
New Limits Set on Chirality Researchers have set a new standard in stereochemistry. Measuring Raman optical activity, they have confirmed the spatial arrangement of a molecule with almost impossibly subtle chirality: (R)-[ 2H 1, 2H 2, 2H 3]-neopentane. mark for My Articles similar articles
Chemistry World
September 17, 2008
Hayley Birch
Colloids twist like DNA French scientists have used magnetic colloids to make self-assembling, helical structures reminiscent of DNA mark for My Articles similar articles
Chemistry World
February 6, 2015
Elisabeth Ratcliffe
Exploiting the chirality of DNA DNA has emerged as an innovative way of controlling the chirality of a reaction product by binding catalysts in such a way that one enantiomer is preferentially generated. mark for My Articles similar articles
Chemistry World
February 21, 2007
Tom Westgate
Complex Organic Molecules Teamed with Iodine Chemists have developed a method for constructing complex halogen-containing organic molecules from simple compounds in a single step. The discovery could pave the way for the synthesis of many potentially useful naturally occurring molecules. mark for My Articles similar articles
Chemistry World
November 26, 2010
Amaya Camara-Campos
Enriching the origin of life theory An enantioenrichment of the amino acid valine, which could shed light on the origin of chirality on Earth, has been achieved by scientists in Spain. mark for My Articles similar articles
Chemistry World
July 26, 2007
Tom Westgate
Counterion Does the Twist US chemists have achieved a breakthrough in the design of catalysts that selectively produce chiral compounds. mark for My Articles similar articles
Chemistry World
July 24, 2009
Nina Notman
Chiral isotropic liquids from achiral molecules Boomerang-shaped liquid crystal phase molecules that don't exhibit 'handedness' (chirality) have been found to form unusual chiral structures that spontaneously separate into left- and right-handed domains. mark for My Articles similar articles
Chemistry World
July 30, 2013
Paul Docherty
Melotenine A Chirality, where would we be without you? Often the bane of the synthetic chemist's life, the challenge of asymmetry is perhaps what makes total synthesis so endlessly intriguing. mark for My Articles similar articles
Chemistry World
November 6, 2009
Phillip Broadwith
Enzyme binds both sides of the mirror European chemists have discovered that both mirror-image forms of a particular compound can bind at the same time in the same site of an enzyme, a phenomenon that has never been seen before. mark for My Articles similar articles
Chemistry World
November 1, 2009
Hayley Birch
How light gave life a helping hand A new theory for how 'handedness' in organic molecules evolved has been proposed by Dutch scientists. mark for My Articles similar articles
Chemistry World
December 17, 2009
Simon Hadlington
Single catalyst gives two products from racemic mixture Chemists in the US have demonstrated a remarkable reaction in which a single catalyst can transform a racemic mixture - molecules identical in every way except for their chirality - into two distinct enantiomerically pure products. mark for My Articles similar articles
Chemistry World
September 6, 2013
Melissae Fellet
Unravelling stereochemistry via mass spectrometry Researchers have used mass spectrometry to determine the stereochemistry of a prototypical chiral molecule, CHBrClF. mark for My Articles similar articles
Chemistry World
March 8, 2011
Jon Cartwright
Carbon nanotubes - a boon for chiral catalysts Researchers in China have created a new catalyst that could help in the production of chiral molecules for medical drugs. The catalyst, which consists of platinum nanoparticles encapsulated in carbon nanotubes, is the most active of its type ever reported. mark for My Articles similar articles
Chemistry World
April 29, 2009
James Urquhart
Huge pores in zeolite molecular sieve Researchers in Spain and Sweden have synthesized and structurally determined a new kind of crystalline molecular sieve with extra large holes and chiral properties. mark for My Articles similar articles
Chemistry World
May 26, 2015
Victoria Richards
Crystalline sponge method strikes again Scientists from Japan report that their revolutionary crystallographic technique has determined the stereochemistries of molecules with axial and planar chiralities, where classical methods had failed. mark for My Articles similar articles
Chemistry World
September 25, 2014
Hayley Simon
Breakup reaction hints at handedness of nature The breakup of 3-bromocamphor molecules bombarded by polarized electrons has given a tantalizing hint of the origins of biological homochirality -- nature's preference for one mirror image of a molecule over another. mark for My Articles similar articles
Chemistry World
May 30, 2013
Andy Extance
Catalyst duo exerts powerful stereocontrol Chemists from the Swiss Federal Institute of Technology, ETH Zurich, have teamed chiral catalysts in pairs to selectively drive a reaction towards desired stereoisomeric products with high selectivity. mark for My Articles similar articles
Chemistry World
June 15, 2015
Tim Wogan
Long range chirality transfer observed A new method to detect biomolecules by using a plasmonic nanoparticle to transfer their chirality onto an achiral dye has been developed by researchers mark for My Articles similar articles
Chemistry World
December 10, 2008
Simon Hadlington
Alcohol enantiomer conundrum cracked UK chemists have discovered a straightforward new way to make chiral tertiary alcohols that gives selective access to either enantiomer. mark for My Articles similar articles
Chemistry World
May 9, 2010
Phillip Broadwith
Iron catalyst breaks the mold An iron catalyst that is not only greener than many of its precious metal competitors, but also catalyses reactions that they can't, could open new avenues in transition metal catalysis, say Chinese researchers. mark for My Articles similar articles
Chemistry World
September 20, 2007
Lewis Brindley
New Catalyst Rings the Changes Organic chemists in the US have developed a method to control the stereochemistry of a useful intramolecular Diels-Alder reaction. mark for My Articles similar articles
Chemistry World
May 24, 2013
David Bradley
Microwaves show their hand The chirality of a gas phase molecule held in an electric field can be revealed using microwave spectroscopy. Hooking the technique to a separation step might even be exploited to isolate a specific enantiomer from a racemic mixture of both forms. mark for My Articles similar articles
Chemistry World
April 28, 2009
Jon Cartwright
Metal ions give rise to threaded molecules Chemists in France have developed a simple method to synthesize tricky '[3]rotaxane' molecules for potential applications in intelligent materials and molecular machines. mark for My Articles similar articles
Chemistry World
October 18, 2011
Steve Down
Cofactor Control of Catalysis Enantioselectivity Scientists have used cofactors to control the enantioselectivity of supramolecular transition metal catalysts, enabling the asymmetric hydrogenation of a series of acrylates and related compounds with remarkably high selectivities. mark for My Articles similar articles
Chemistry World
June 2010
Paul Docherty
Column: Totally Synthetic Although its chemistry is mature and varied, my use of silicon reagents in my synthetic forays has been limited to a somewhat clumsy use of hydroxyl protecting groups. mark for My Articles similar articles
Chemistry World
January 24, 2007
Lionel Milgrom
Chemical Computing Creates World's Densest Data Storage Medium A vital piece of nanoelectronic circuitry has been produced which could bring molecular computers a step closer. mark for My Articles similar articles
Chemistry World
June 10, 2010
Phillip Broadwith
A green and salty chiral catalyst An efficient, chiral, salt-based hypervalent iodine catalyst has been discovered by Japanese chemists that could replace toxic metal catalysts without generating the waste or explosion risks associated with hypervalent organo-iodine complexes. mark for My Articles similar articles
Chemistry World
June 17, 2010
Andrew Turley
Biocatalyst improves diabetes drug production Researchers have developed an enzyme that can produce a difficult to form chiral amine in a best-selling diabetes therapy. mark for My Articles similar articles
Chemistry World
June 13, 2008
Richard Van Noorden
Asymmetric ketone catalysis gets pharma-scale makeover An asymmetric catalysis reaction limited to laboratory syntheses has received a makeover that could see it used on a large scale by drug-makers. mark for My Articles similar articles
Chemistry World
June 18, 2014
Michael Parkin
Separation by levitation A team in the US has shown that enantiopure and racemic crystals can be separated by magnetic levitation. mark for My Articles similar articles
Chemistry World
November 2, 2015
Batzelladine B Of all the diverse substances that nature produces, the alkaloids -- small molecules containing basic nitrogen -- have had the greatest impact on human history and health. mark for My Articles similar articles
Chemistry World
March 23, 2009
Hayley Birch
Speeding up screening for chiral catalysts U.S. researchers say their method represents a 'standard workhorse' for discovery and optimisation of chiral catalysts, such as those widely used by the pharmaceutical and pesticide industries. mark for My Articles similar articles
Chemistry World
June 16, 2010
Simon Hadlington
Rotaxane molecule seen in action Researchers from the US and Japan have directly observed the ring of a rotaxane molecule shuttling along its spindle. The behaviour of the rotaxane is influenced by its molecular environment, something that is significant if the molecules are to be used as molecular machines. mark for My Articles similar articles
Chemistry World
February 21, 2008
Lewis Brindley
Esters Made Easy with Indium Indium is the basis of a novel catalyst designed to make useful cyclic esters. This catalyst could greatly simplify the production of chiral dihydropyranones, important structural elements in many natural products and pharmaceuticals. mark for My Articles similar articles
Reactive Reports
Issue 33
David Bradley
Two-faced Liquid Crystals A new class of programmable liquid crystals could be used to make variable optical filters for laboratory instrumentation and digital cameras; they might even be used to treat dyslexia. mark for My Articles similar articles
Chemistry World
April 18, 2010
Simon Hadlington
First DNA rotaxane Rotaxanes are dumbbell-shaped molecules encircled by a molecular hoop that can move unhindered along the axle, trapped by the bulky stoppers at either end. These could be useful components in molecular machines. mark for My Articles similar articles
Chemistry World
September 6, 2006
Michael Gross
Selective Shortcut Chemists have developed a simple catalyst that speeds up the synthesis of a chiral protected building block used in many complex syntheses. mark for My Articles similar articles
Chemistry World
May 15, 2014
Jenifer Mizen
Freeze-dried cells make better biocatalysts A biocatalytic cascade using mashed-up cells has overcome extraction and solubility problems associated with using enzymes in chemical syntheses. mark for My Articles similar articles