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Chemistry World
October 12, 2007
James Mitchell Crow
Flow Reactors Enter the Rapids Continuous flow chemistry's promise to shake up synthesis gathered momentum this month, with the first Uniqsis Flow Chemistry Symposium. mark for My Articles similar articles
Chemistry World
March 2011
Microwave chemistry - green or not? Microwave-assisted chemistry might not deserve its environmentally friendly reputation, argues Jonathan Moseley mark for My Articles similar articles
Chemistry World
November 25, 2014
James Urquhart
Nanomolar chemistry enables 1500 experiments in a single day Chemists have conducted over 1500 chemistry experiments in under a day thanks to a miniaturized, high throughput automation platform they developed for identifying how synthetic molecules react under various conditions. mark for My Articles similar articles
Chemistry World
October 22, 2013
Marie Cote
Oliver Kappe: Freedom to explore Oliver Kappe is professor of chemistry at the University of Graz in Austria. Research in the Kappe group focuses on enabling technologies for synthesis, including microwave and continuous flow methods. mark for My Articles similar articles
Chemistry World
February 20, 2013
Amy Middleton-Gear
Ohmic heating for efficient green synthesis Portuguese scientists have developed a new ohmic-heating reactor for organic syntheses on water, or chemistry using an aqueous suspension of the reactants. mark for My Articles similar articles
Chemistry World
September 19, 2008
Lewis Brindley
Chemical conversion made twice as green A combination of two green processes - supercritical fluids and photochemistry - could have a bright future for performing environmentally friendly reactions on an industrial scale mark for My Articles similar articles
Chemistry World
March 8, 2009
Nina Notman
Polymer Crossroads Act as Tiny Reactors Scientists in the US have taken inspiration from a Dutch painter to create ultrasmall chemical reactors at the junctions of overlapping polymer nanofibres mark for My Articles similar articles
Chemistry World
December 5, 2012
Phillip Broadwith
Chemical reactions in hot water Chinese and Japanese chemists have highlighted hot water's ability to promote unexpected reactions without any other reagents or catalysts. The work should expand our understanding of how to harness the physicochemical properties of water to potentially replace more complex reagents and catalysts. mark for My Articles similar articles
Chemistry World
November 2007
Derek Lowe
Column: In the Pipeline Chemists are finally going with the flow. mark for My Articles similar articles
Chemistry World
April 30, 2013
Andy Extance
Microreactors tame osmium tetroxide Researchers in South Korea and India have made microfluidic reactors that safely harness the synthetically powerful but noxious catalyst osmium tetroxide. mark for My Articles similar articles
Chemistry World
June 24, 2010
Phillip Broadwith
Aryl rings get a fluorine fix A mild and effective method for coupling trifluoromethyl groups on to aryl rings has been developed by US chemists. mark for My Articles similar articles
Chemistry World
October 23, 2013
Emma Eley
Synthesis by sunlight Sustainable oxidation reactions can be performed with inexpensive and readily available photovoltaic cells mark for My Articles similar articles
Chemistry World
November 1, 2012
Laura Howes
Shining new light on the Ullmann reaction Ullmann C -- N coupling -- a copper mediated carbon -- nitrogen coupling reaction used to create arylamines -- is one of the most widely used reactions in the pharmaceutical industry. mark for My Articles similar articles
Chemistry World
February 2, 2012
Elinor Richards
Magical microwaves Microwaves have been used to promote organic reactions since the 1980s and they can lead to higher yields and shorter reaction times than conventional heating, but why? mark for My Articles similar articles
Chemistry World
October 2007
Derek Lowe
In the Pipeline One of the biggest areas of chemical research these days is in catalytic processes. It's one of the places we can really improve our processes, especially when you count the waste stream (as you should) as part of the total energy bill. mark for My Articles similar articles
Chemistry World
August 16, 2009
Tom Bond
Catalyst free carbon-carbon bond formation The method offers an environmentally friendly way to form one of the most important bonds in organic synthesis. mark for My Articles similar articles
Chemistry World
August 26, 2010
Simon Hadlington
A self-optimising microreactor system Chemists in the US have developed a microreactor system which automatically calculates the optimal conditions for the chemical reaction it is undertaking. mark for My Articles similar articles
Chemistry World
April 18, 2012
Elinor Richards
Homogeneous Catalyst Recovery Made Easier Scientists have now found a way to recover homogeneous catalysts at the end of a chemical reaction that doesn't suffer from the slow reaction rates that affect current catalyst recovery systems. mark for My Articles similar articles
Chemistry World
October 23, 2013
Manisha Lalloo
NMR thermometer takes reactor's temperature Scientists in the US have used NMR to create temperature maps of reactions taking place inside catalytic reactors. Their technique opens the door to an easy, non-invasive way to discover hot and cold 'spots' inside reactors. mark for My Articles similar articles
Chemistry World
May 26, 2015
Catching the runaways I think each cohort of industrial chemists has a runaway industrial reaction that defines their generation. mark for My Articles similar articles
Chemistry World
September 28, 2015
Karl Collins
A witches' brew for trifluoromethylation Trifluoromethylating phenols is one example of a reaction that would be incredibly useful when attempting to tune the chemical and biological properties of molecules for pharmaceutical and agrochemical research. mark for My Articles similar articles
Chemistry World
October 2, 2009
Phillip Broadwith
Microwave effect ruled out Microwave reactions in silicon carbide vials - which are heated by microwaves but shield the contents from radiation - have confirmed that most of the benefits seen in microwave-assisted chemistry are purely due to heating mark for My Articles similar articles
Chemistry World
August 12, 2015
Matthew Gunther
Chemists hold a candle to reagent preservation Scientists in the US now have a solution to end the build-up of chemical waste with a wax capsule that can protect reagents from the atmosphere. mark for My Articles similar articles
Chemistry World
September 2011
Paul Docherty
Column: Totally Synthetic Corey Stephenson of Boston University is an expert a type of reaction called photochemical reduction-oxidation. He has charmed photons into performing many chemical tricks, but one is a photoredox dehalogenation using blue light and a ruthenium bipyridyl catalyst. mark for My Articles similar articles
Chemistry World
January 17, 2014
Katia Moskvitch
Life may have begun in a tiny water droplet Chemical reactions run much faster and more efficiently when they take place in tiny droplets rather than in freestanding water -- such as a puddle or a lake, say researchers. mark for My Articles similar articles
Chemistry World
August 22, 2014
Derek Lowe
Death of a reagent Anyone who's been practicing organic chemistry for a while can think back to reactions and reagents that were once in far wider use than they are today. mark for My Articles similar articles
Chemistry World
October 15, 2015
Aurora Walshe
Carbon dioxide sees the light Collaborators in Spain and Germany have built a microreactor that uses visible light to drive a reaction that turns carbon dioxide into carbon monoxide -- an important chemical building block. mark for My Articles similar articles
Chemistry World
January 25, 2013
Derek Lowe
Name reactions: how does the label stick? Some of these names go back to the 19th century, and many more of them come from the first decades of the 20th. Once in a while, I wonder if the tradition is dying out. Are we still naming chemical reactions after their discoverers? mark for My Articles similar articles
Chemistry World
March 24, 2015
Karl Collins
Back to basics for silylation While silicon is probably most familiar in organic synthesis as part of protecting groups, its utility extends much further. mark for My Articles similar articles
Chemistry World
November 2010
Carbon Couplers Take the Prize Three giants of organic chemistry, who pioneered palladium-catalysed cross coupling reactions, have shared this year's Nobel prize. mark for My Articles similar articles
Chemistry World
January 29, 2014
Elisabeth Ratcliffe
Flow system overcomes reagent incompatibility issues Synthesizing cyclic carbonates could become easier and more efficient thanks to a sequential flow system developed by scientists in the US. mark for My Articles similar articles
Chemistry World
March 21, 2007
Richard Van Noorden
Forcing a Reaction US chemists have forced molecules to react by ripping their bonds apart with ultrasound. The scientists carefully stretched one targeted bond until it snapped, guiding the molecule's subsequent reaction into pathways forbidden by conventional chemistry. mark for My Articles similar articles
Chemistry World
September 26, 2012
Derek Lowe
Under pressure Someone interviewing for a synthetic chemistry position had better know his or her organic chemistry. It's fair to ask questions that will make sure of that. But does a candidate need to know the curly-arrow details of reactions that they'll never run? mark for My Articles similar articles
Chemistry World
May 8, 2012
Phillip Broadwith
Keep stirring that Suzuki The shape of your reaction vessel can influence the behavior of organotrifluoroborate compounds in Suzuki cross-coupling reactions, say chemists in the UK. mark for My Articles similar articles
Chemistry World
January 25, 2008
Simon Hadlington
Catalysis Probed with MRI Scientists have developed a way of peering into a microreactor to watch gases react on a solid catalyst. mark for My Articles similar articles
Chemistry World
October 15, 2012
Melissae Fellet
Synthesis by mass spectrometry Chemists have used mass spectrometry, commonly used to analyze molecules, to synthesize them on the microscale. mark for My Articles similar articles
Chemistry World
August 28, 2014
Trekking across chemical frontiers Thinking about getting molecules to where they need to go is a new concept for the novice process chemist, but is familiar to chemical engineers as mass transfer. mark for My Articles similar articles
Chemistry World
July 3, 2015
Andy Extance
Copper catalysis overcomes double bond trouble Some carbon-carbon double bonds seem too unreactive for synthetic use -- but that's just how chemists in the US are now exploiting them. mark for My Articles similar articles
Chemistry World
July 14, 2009
Phillip Broadwith
Multicomponent reactions step up a gear Dutch chemists have taken multicomponent reactions to the next level, combining a total of eight different starting materials in a single flask, bringing together three different multicomponent reactions and making nine new bonds in a single step. mark for My Articles similar articles
Chemistry World
October 2009
Column: In the pipeline Derek Lowe discusses the problem of leaning too heavily on favorite reactions mark for My Articles similar articles
Chemistry World
July 22, 2013
Anthony King
Microwave quarrel heats up A brouhaha over microwave heating in organic reactions has escalated after the two research groups involved penned barbed correspondences aimed at each other's approaches in Angewandte Chemie. mark for My Articles similar articles
Chemistry World
August 6, 2014
Simon Hadlington
3D printed reactionware hots up UK researchers have shown that it is possible to carry out a range of hydrothermal chemical syntheses in sealed reactors made from 3D printed polypropylene. mark for My Articles similar articles
Chemistry World
March 20, 2008
James Mitchell Crow
Surfactants Help Reactions Work in Water Scientists have discovered a surfactant that allows the catalytic organic reactions commonly used to assemble organic structures such as drug molecules to be run in water. mark for My Articles similar articles
Chemistry World
May 22, 2015
James Urquhart
Complex amines made easy (and cheap) Phil Baran's lab at the Scripps Research Institute, La Jolla, has come up with a protocol that repurposes two readily available and inexpensive feedstock building blocks; olefins and nitroarenes, via iron-catalysed cross-coupling. mark for My Articles similar articles
Chemistry World
July 31, 2014
Helen Bache
Tracking complex reactions in space and time Scientists in Taiwan have put together a system that uses a computer screen and digital camera to obtain spatial, temporal and spectral information on reaction samples, for a low cost. mark for My Articles similar articles
Reactive Reports
Issue 67
David Bradley
Multichannel Microchemical Factory The microchemical factory approach offers a safer and scaleable approach to producing materials from the very smallest quantities to the largest bulk. mark for My Articles similar articles
Chemistry World
July 23, 2015
Richard Massey
Photoredox catalysis mechanisms seen in new light A debate over whether photoredox-catalyzed reactions proceed via chain processes may now be settled, thanks to new mechanistic insight brought to light by scientists in the US. mark for My Articles similar articles
Chemistry World
November 5, 2015
Emma Stoye
Unnatural nanoreactor puts click reaction in the spotlight A protein 'nanoreactor' that can monitor a click chemistry reaction at the level of single molecules has been created by adding an unnatural amino acid to a nanopore. mark for My Articles similar articles
Chemistry World
November 6, 2008
James Mitchell Crow
Double reactor makes hydrogen and syngas Two chemical reactions key to producing future fuels can be linked together in a single membrane-based reactor to increase their efficiency, say Chinese chemists. mark for My Articles similar articles
Chemistry World
February 20, 2012
James Urquhart
Unusual kinetics of catalyst revealed US researchers have elucidated the unusual reaction kinetics of C-H activation by the palladium(II) catalyst (Pd(OAc) 2). mark for My Articles similar articles