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Chemistry World
November 28, 2013
Andy Extance
Base metal catalysts strike hydrogenation gold Three teams have shown that chemists need not rely only on expensive and toxic precious metal catalysts for hydrogenation -- they've found complementary alternatives based on cheap, abundant and safer transition metals. mark for My Articles similar articles
Chemistry World
June 27, 2013
Emma Eley
Sustainable iron catalyst for clean hydrogenation An international team of chemists has reported a clean and green way to perform one of the most important industrial reactions for pharmaceutical and petrochemical synthesis. mark for My Articles similar articles
Chemistry World
July 26, 2007
Tom Westgate
Counterion Does the Twist US chemists have achieved a breakthrough in the design of catalysts that selectively produce chiral compounds. mark for My Articles similar articles
Chemistry World
December 23, 2015
Karl Collins
Scratching chiral surfaces There are numerous challenges to developing reactions that exploit chiral surfaces, or employ molecular modifiers (ligands) to create a chiral surface environment and control the stereoselectivity of a transformation. mark for My Articles similar articles
Chemistry World
April 19, 2009
Hayley Birch
Chiral metals shape up for catalysis Dutch and Israeli scientists have found a way to induce the chirality usually only found in organic materials in palladium. mark for My Articles similar articles
Chemistry World
February 20, 2012
James Urquhart
Unusual kinetics of catalyst revealed US researchers have elucidated the unusual reaction kinetics of C-H activation by the palladium(II) catalyst (Pd(OAc) 2). mark for My Articles similar articles
Chemistry World
May 30, 2013
Andy Extance
Catalyst duo exerts powerful stereocontrol Chemists from the Swiss Federal Institute of Technology, ETH Zurich, have teamed chiral catalysts in pairs to selectively drive a reaction towards desired stereoisomeric products with high selectivity. mark for My Articles similar articles
Chemistry World
October 16, 2015
Philippa Matthews
One pot recipe for incompatible catalytic transformations Researchers from the US have demonstrated a new catalyst support structure allowing two incompatible catalysts to work in tandem. mark for My Articles similar articles
Chemistry World
November 7, 2014
Katrina Kramer
Stressed ligands switch catalysis selectivity Researchers have discovered that enantioselectivity in palladium-catalyzed reactions depends on the ligand's intramolecular strain. mark for My Articles similar articles
Chemistry World
February 21, 2008
Lewis Brindley
Esters Made Easy with Indium Indium is the basis of a novel catalyst designed to make useful cyclic esters. This catalyst could greatly simplify the production of chiral dihydropyranones, important structural elements in many natural products and pharmaceuticals. mark for My Articles similar articles
Chemistry World
June 1, 2006
Michael Gross
New Twists on Catalysis Chemists around the world have discovered several new twists to improve the performance of asymmetric catalysts in hydrogenation reactions. mark for My Articles similar articles
Chemistry World
March 8, 2011
Jon Cartwright
Carbon nanotubes - a boon for chiral catalysts Researchers in China have created a new catalyst that could help in the production of chiral molecules for medical drugs. The catalyst, which consists of platinum nanoparticles encapsulated in carbon nanotubes, is the most active of its type ever reported. mark for My Articles similar articles
Chemistry World
June 10, 2010
Phillip Broadwith
A green and salty chiral catalyst An efficient, chiral, salt-based hypervalent iodine catalyst has been discovered by Japanese chemists that could replace toxic metal catalysts without generating the waste or explosion risks associated with hypervalent organo-iodine complexes. mark for My Articles similar articles
Chemistry World
October 18, 2011
Steve Down
Cofactor Control of Catalysis Enantioselectivity Scientists have used cofactors to control the enantioselectivity of supramolecular transition metal catalysts, enabling the asymmetric hydrogenation of a series of acrylates and related compounds with remarkably high selectivities. mark for My Articles similar articles
Chemistry World
November 17, 2008
Simon Hadlington
Catalyst flexes for extra control US chemists have developed a new type of catalyst capable of exerting high stereochemical control over olefin metathesis reactions mark for My Articles similar articles
Chemistry World
October 22, 2009
Simon Hadlington
Carbenes catalyse metal-metal bonds in organometallics Chemists in the US have discovered a novel way to transform organometallic compounds so that new metal-metal bonds are created. mark for My Articles similar articles
Chemistry World
August 16, 2009
Tom Bond
Catalyst free carbon-carbon bond formation The method offers an environmentally friendly way to form one of the most important bonds in organic synthesis. mark for My Articles similar articles
Chemistry World
January 8, 2014
Karl Collins
Oxidation station Small molecules are making significant inroads -- with reactivity and selectivity approaching levels previously thought unachievable. mark for My Articles similar articles
Chemistry World
April 7, 2015
Hugh Cowley
The Goldilocks of heterogeneous catalysis An international team of scientists has tethered palladium to a metal -- organic framework support using thiol groups normally associated with catalyst poisoning mark for My Articles similar articles
Chemistry World
November 1, 2007
Richard Van Noorden
Step Change for Organic Synthesis US chemists discovered how to attack a complex molecule's unreactive carbon-hydrogen bonds, without resorting to wasteful synthetic aids like protecting and directing groups. mark for My Articles similar articles
Chemistry World
September 20, 2007
Lewis Brindley
New Catalyst Rings the Changes Organic chemists in the US have developed a method to control the stereochemistry of a useful intramolecular Diels-Alder reaction. mark for My Articles similar articles
Chemistry World
April 25, 2010
Hayley Birch
New strategy yields best ever catalyst for ammonia decomposition US researchers have developed a new strategy for predicting bimetallic catalysts. mark for My Articles similar articles
Chemistry World
October 3, 2008
Lewis Brindley
Nanotube catalysts improve industrial reaction A catalyst consisting of modified carbon nanotubes makes an important industrial reaction milder, safer and more selective, according to researchers in Germany. mark for My Articles similar articles
Chemistry World
August 11, 2010
Simon Hadlington
Non-metal-catalysed C-C coupling Chinese chemists have successfully coupled aromatic molecules without the use of a transition metal catalyst - something that people have been trying to do for years with little success. mark for My Articles similar articles
Chemistry World
July 20, 2006
Jessica Ebert
Golden Touch for Amines Aminobenzene chemicals are used to make anything from dyes to pharmaceuticals, and now scientists have found a way to produce them in a more efficient way using a gold catalyst. mark for My Articles similar articles
Chemistry World
June 7, 2009
Phillip Broadwith
Pd(III) catalysis insight The discovery of a bimetallic palladium(III) complex that can catalyse the formation of carbon-heteroatom bonds adds a new facet to our understanding of the chemistry of one of the most widely-used metals in catalysis, say US chemists. mark for My Articles similar articles
Chemistry World
October 15, 2015
Emma Stoye
Cobalt could cut costs for pharma ingredients A new kind of cobalt catalyst can be used in the hydrogenation of esters and carboxylic acids to alcohols without the need for extremely high temperatures or expensive precious metals. mark for My Articles similar articles
Chemistry World
February 6, 2015
Elisabeth Ratcliffe
Exploiting the chirality of DNA DNA has emerged as an innovative way of controlling the chirality of a reaction product by binding catalysts in such a way that one enantiomer is preferentially generated. mark for My Articles similar articles
Chemistry World
September 6, 2006
Michael Gross
Selective Shortcut Chemists have developed a simple catalyst that speeds up the synthesis of a chiral protected building block used in many complex syntheses. mark for My Articles similar articles
Chemistry World
December 12, 2007
Jonathan Edwards
Aqueous Fischer-Tropsch is Clean and Green Chinese chemists have carried out the Fischer-Tropsch reaction in water for the first time, bringing a greener route to hydrocarbon fuels a step closer. mark for My Articles similar articles
Chemistry World
June 2007
Dylan Stiles
Opinion: Bench Monkey This PhD student takes an organic chemist's tour around the periodic table. mark for My Articles similar articles
Chemistry World
July 3, 2015
Andy Extance
Copper catalysis overcomes double bond trouble Some carbon-carbon double bonds seem too unreactive for synthetic use -- but that's just how chemists in the US are now exploiting them. mark for My Articles similar articles
Chemistry World
October 31, 2014
Andy Extance
Acid choice flips enantioselectivity Organic chemists in Ireland have developed a pair of reactions they think are unique in producing predominantly one of two mirror-image products without a change of catalyst. mark for My Articles similar articles
Chemistry World
September 4, 2013
Mark Peplow
Iron catalyst offers nitrogenase clues It is one of the most enduring mysteries in chemistry: how do certain bacteria fix nitrogen from the air? mark for My Articles similar articles
Chemistry World
November 2010
Carbon Couplers Take the Prize Three giants of organic chemistry, who pioneered palladium-catalysed cross coupling reactions, have shared this year's Nobel prize. mark for My Articles similar articles
Chemistry World
January 6, 2010
Phillip Broadwith
Enzymes do the twist The way enzyme catalysts bind molecules to speed up their reactions is not as simple as once thought, say chemists from the UK and Spain. mark for My Articles similar articles
Chemistry World
March 20, 2007
Tom Westgate
Is Your Lab Ready to go Veggie? In a recently published review article, Geoffrey Cordell demonstrates that the greengrocer's could be an unexpected goldmine of sustainable, cheap reagents that would benefit chemistry in developing countries. mark for My Articles similar articles
Chemistry World
November 10, 2011
David Bradley
A soluble solution to the Haber process? A clearer understanding of the activity of the key component of the Haber-Bosch process - the catalyst - could help to optimize industrial nitrogen fixation still further and remove the need for high temperatures and pressures. mark for My Articles similar articles
Chemistry World
December 17, 2009
Simon Hadlington
Single catalyst gives two products from racemic mixture Chemists in the US have demonstrated a remarkable reaction in which a single catalyst can transform a racemic mixture - molecules identical in every way except for their chirality - into two distinct enantiomerically pure products. mark for My Articles similar articles
Chemistry World
February 13, 2013
James Mitchell Crow
Tapping proton power for enantioselective synthesis A simple proton is the key to a novel approach by US-based chemists to synthesize chiral amines and alcohols -- a structural motif common to many organic molecules with pharmaceutical promise. mark for My Articles similar articles
Chemistry World
February 6, 2011
Laura Howes
Cells as test tubes Chemists have used living cells as test tubes to carry out chemical reactions never before seen within living cells. mark for My Articles similar articles
Chemistry World
July 15, 2010
Simon Hadlington
Synthetic enzyme catalyses Diels-Alder reaction The reaction is key to many organic syntheses and suggests that artificial enzymes could soon become part of the synthetic chemist's toolkit. mark for My Articles similar articles
Chemistry World
October 10, 2007
Ned Stafford
Catalytic Converters go Nano Mazda Motor Corporation has unveiled a new generation of catalytic converters that use 70 to 90 per cent less of the precious metals which help to purify exhaust emissions. mark for My Articles similar articles
Chemistry World
February 24, 2011
James Urquhart
Elusive form of iron captured Researchers in the US and Germany have synthesised and characterised an iron nitride compound that reacts with water to produce high yields of ammonia under mild conditions. mark for My Articles similar articles
Chemistry World
October 22, 2008
Susan Aldridge
A greener route to amines Researchers based in Israel have developed an easier way to make troublesome primary amines, using a new ruthenium catalyst. mark for My Articles similar articles
Chemistry World
October 1, 2014
Karl Collins
Twisting activity from amides When I think of asymmetric aldol reactions, what immediately springs to mind is using boron to control enolate geometry and chiral auxiliaries to impart facial selectivity in the addition step. mark for My Articles similar articles
Chemistry World
December 3, 2009
Hayley Birch
Bio-Inspired Catalyst Design Could Rival Platinum French scientists have demonstrated the potential of a new fuel cell catalyst inspired by hydrogenase enzymes. mark for My Articles similar articles
Chemistry World
November 27, 2009
Simon Hadlington
A simple way to join an olefin to an arene Chemists in the US have developed a simple and effective way to carry out a key class of reaction in organic synthesis - the bolting an olefin to an aromatic ring. mark for My Articles similar articles
Chemistry World
September 23, 2010
Jon Cartwright
Catalyst improves prospects for fuel cells Chemists in the US have developed a new catalyst that could help in a key reaction used to generate hydrogen for fuel cells. mark for My Articles similar articles
Chemistry World
January 10, 2014
Jennifer Newton
Nitrenium hugs stabilize positively rare complexes Everyone knows that like charges repel one another. But unusual coordination compounds bearing cationic ligands bound to cationic metals have been prepared by scientists in Israel, opening up fresh opportunities for organic transformations. mark for My Articles similar articles