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Chemistry World June 14, 2012 David Bradley |
Tripling up on boron bonds Carbon and nitrogen are well known for their triple bonds, but making stable compounds with a triple bond between two boron atoms hadn't been achieved despite the computational possibilities. Until now. |
Chemistry World October 29, 2009 Phillip Broadwith |
Two metals are better than one UK chemists have developed reagents that can metallate ethers and ethene at room temperature without them disintegrating. |
Chemistry World December 13, 2009 Lewis Brindley |
Breaking the strongest bonds Chemists have uncovered a way to sever two of the strongest bonds in chemistry - in dinitrogen and carbon monoxide - and make useful organic compounds. |
Chemistry World February 21, 2007 Tom Westgate |
Complex Organic Molecules Teamed with Iodine Chemists have developed a method for constructing complex halogen-containing organic molecules from simple compounds in a single step. The discovery could pave the way for the synthesis of many potentially useful naturally occurring molecules. |
Chemistry World January 19, 2010 Simon Hadlington |
New 'click' reaction to modify proteins Chemists in the US have discovered a new way to attach small molecules to proteins and peptides under mild, aqueous reaction conditions. |
Wired Erin Biba |
Molecular Frameworks, the Building Blocks of All Life The world is complicated, but not as complicated as you might think. Most organic molecules derive from a few relatively simple architectures. |
Chemistry World July 2007 Dylan Stiles |
Opinion: Bench Monkey Synthesizing molecules that force atoms into bizarre contortionist acts is the only way to learn. |
Chemistry World April 14, 2009 Lewis Brindley |
Osmium and pyridine ring together Organic chemists in China have found a way to put osmium into a pyridine ring - leading to the synthesis of the first metallapyridinium complex. |
Chemistry World January 20, 2010 James Urquhart |
Disilicate synthesis success A compound containing a stable silicon-silicon bond between two negatively charged pentacoordinated silicon atoms - silicates - has been synthesized and isolated for the first time by Japanese researchers. |
Reactive Reports Issue 54 David Bradley |
Metals Take on Carbon's Bonding Characteristics A rethink about chemical bonding might be in the cards thanks to research that shows that the metal indium forms bonds in a manner not dissimilar to organic carbon atoms. |
Chemistry World April 26, 2007 Richard Van Noorden |
Hydrogen Busters go Synthetic Chemists have created a small molecule which mimics the way natural enzymes chew up hydrogen. The model should inspire designs for new catalysts that can break up hydrogen in fuel cells; or (running in reverse) help produce the fuel for a hydrogen economy. |
Chemistry World January 6, 2010 Phillip Broadwith |
Enzymes do the twist The way enzyme catalysts bind molecules to speed up their reactions is not as simple as once thought, say chemists from the UK and Spain. |
Chemistry World August 30, 2007 James Mitchell Crow |
Toxins' Synthesis Secret Cracked US chemists have discovered that using water instead of organic solvents is the key to understanding how algae make toxins called ladder polyethers. |
Chemistry World June 23, 2015 Philip Ball |
Ultra-bright x-rays film molecular reaction A team working at the Stanford Linear Collider in California claims to have made 'the first molecular movie' using ultra-fast x-ray scattering from molecules as they undergo a chemical reaction. |
Chemistry World January 25, 2007 Richard Van Noorden |
Water Surprise for Atmospheric Scientists Lone water molecules can catalyze reactions between atmospheric gases, scientists have confirmed, throwing a wrench in the works of supposedly simple atmospheric chemistry. |
Chemistry World November 3, 2008 Simon Hadlington |
Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple? |
Chemistry World March 21, 2007 Richard Van Noorden |
Forcing a Reaction US chemists have forced molecules to react by ripping their bonds apart with ultrasound. The scientists carefully stretched one targeted bond until it snapped, guiding the molecule's subsequent reaction into pathways forbidden by conventional chemistry. |
Chemistry World June 1, 2006 Michael Gross |
New Twists on Catalysis Chemists around the world have discovered several new twists to improve the performance of asymmetric catalysts in hydrogenation reactions. |
Chemistry World May 29, 2015 Derek Lowe |
Magic molecule modifiers The synthesis of a new organic molecule can be approached in several ways. |
Chemistry World March 9, 2006 Katharine Sanderson |
Covalent Bonds Crack Under the Strain Chemists must consider engineering principles when designing molecules following news that tough carbon-to-carbon bonds break easily under mechanical strain. |
Chemistry World June 2008 Sarah Houlton |
Breaking the rules The author finds out about some chemical tricks that can give a new drug the best possible odds of success |
Chemistry World August 22, 2014 Derek Lowe |
Death of a reagent Anyone who's been practicing organic chemistry for a while can think back to reactions and reagents that were once in far wider use than they are today. |
Chemistry World November 16, 2007 Richard Van Noorden |
Tantalizing Boost for Hydrogen Storage US chemists have announced the discovery of a new hydrogen-storage material, which they say stores large amounts of the gas at room temperature. |
Chemistry World September 29, 2015 |
Navigating chemical space How big is chemistry? I don't mean how important is it, or how many people do it, but rather, how many molecules are there that we could make? |
Chemistry World October 10, 2007 Richard Van Noorden |
Surface Chemistry Wins Nobel Prize The 2007 Nobel Prize in Chemistry has been awarded to German scientist Gerhard Ertl for his work understanding the effect of gas molecules on solid surfaces of metals. |
Chemistry World May 13, 2013 Philip Ball |
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? |
Chemistry World November 2, 2011 Phillip Broadwith |
Do Carbyne Radicals Really Exist in Aqueous Solution? Carbyne radicals are ejected from molybdenum clusters in water and react together to make lots of organic molecules, including alkynes |
Chemistry World July 6, 2006 Michael Gross |
Insecticide Simplified A rapid, flexible way to make variants of potent insecticide molecules known as spinosyns could help to combat the growing problem of insect resistance, according to German chemists. |
Reactive Reports Issue 63 David Bradley |
Chemists Go Round the Bend Chemists often think of molecular wires as "shape-persistent" rods with limited flexibility, but researchers have now shown that molecular wires can be bent into ring shapes. |
Chemistry World July 13, 2015 Philip Ball |
First snapshot of elusive intermediate supplies surprise A team near Zurich in Switzerland, has been able to take a single-molecule snapshot of an intermediate in a common class of organic reactions. |
Chemistry World November 25, 2014 James Urquhart |
Nanomolar chemistry enables 1500 experiments in a single day Chemists have conducted over 1500 chemistry experiments in under a day thanks to a miniaturized, high throughput automation platform they developed for identifying how synthetic molecules react under various conditions. |
Chemistry World March 31, 2009 Lewis Brindley |
Giving molecules a stretch A simple way to stretch small molecules and measure the forces at play has been developed by researchers in the US. |
Reactive Reports Issue 63 David Bradley |
Natural Copy Cat While plants convert carbon dioxide into sugar and oxygen, chemists are having a more difficult time finding an efficient method for converting carbon dioxide into useful fuels. |
Chemistry World October 2009 |
Column: In the pipeline Derek Lowe discusses the problem of leaning too heavily on favorite reactions |
Reactive Reports David Bradley |
Subjective Suboxide Carbon monoxide and carbon dioxide are probably the best known molecules containing just carbon and oxygen, but they do form others, such as carbon suboxide (C3O2), which is one of the most stable. |
Chemistry World January 29, 2015 Santiago Alvarez |
What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept. |
Chemistry World July 16, 2009 Simon Hadlington |
Strange vibrations Researchers in Taiwan have shown that in a relatively simple molecular system the induced vibrations can inhibit the breaking of the bond and slow the reaction down. |
Chemistry World July 31, 2008 |
Nanostructures Made Easy Scotland-based chemists have invented a new way to build nanoscale arrays of molecules over a large surface area: a technique that may be key to making nanostructures in sophisticated sensors, catalysts, and tiny computer parts. |
Chemistry World February 2011 |
Column: In the pipeline Enzymes have been giving chemists inferiority complexes since day one, says Derek Lowe. But there's no denying their potential |
Chemistry World June 2, 2010 Lewis Brindley |
Reactions in a crystal Crystals that can alter their composition without changing the structure of their solid lattice have been developed by US researchers. |
Chemistry World August 2008 |
Column: In the pipeline Problems develop when there are too few workhorse reactions, which may well generate compounds that are too similar to each other. Are we at that stage now? |
Chemistry World November 24, 2006 Richard Van Noorden |
Cooking up Nano-Fusilli Here's a new twist on nanotubes: chemists have found a set of organic molecules that spontaneously assemble themselves into a helical spiral with a hollow core. |
Chemistry World April 7, 2014 Simon Hadlington |
Isolation of cyanoformate suggests new carbon capture approaches The formation of the cyanoformate ion helps to explain why plants' ethylene producing enzymes aren't poisoned by cyanide |
Chemistry World October 15, 2012 Melissae Fellet |
Synthesis by mass spectrometry Chemists have used mass spectrometry, commonly used to analyze molecules, to synthesize them on the microscale. |
Technology Research News August 13, 2003 |
Carbon wires expand nano toolkit Scientists looking for building blocks to form electronics and machines that are not much bigger than molecules have gained a new tool. |
Chemistry World June 12, 2015 David Bradley |
Copper click chemistry mechanism unravelled Both the mono- and bis-copper pathways are active in the CuAAC reaction, but the latter is kinetically favored. |
Chemistry World March 2012 |
Lead-oriented synthesis Ian Churcher and Alan Nadin call for the development of more robust synthetic tools to improve small molecule survival rates in the perilous journey from lead to drug |
Technology Research News October 20, 2004 |
Molecules positioned on silicon Dubbed multi-step feedback control lithography, this new fabrication process could eventually be used to construct prototype molecular electronic devices for future technologies in areas like consumer electronics and biomedical diagnostics. |
Chemistry World August 2007 Derek Lowe |
Opinion: In the Pipeline Process chemists just don't get the credit they deserve. |
Chemistry World January 5, 2011 Akshat Rathi |
Macromolecules from miniature templates UK researchers have designed a new highly effective method to construct large molecules of a defined size using simple templates. |